Determination of ultra trace of thiosemicarbazide by adsorptive stripping voltammetric method

Subject Areas : Journal of the Iranian Chemical Research

Laleh  Hosseinzadeh ¹ (Department of Chemistry, Dezful Branch, Islamic Azad University, Dezful, Iran)
Hossein  Khani ² (Department of Chemistry, Islamic Ilam University, Branch of Ilam, Ilam, Iran)
Shahryar  Abbasi ³ (Department of Chemistry, Islamic Ilam University, Branch of Ilam, Ilam, Iran)

Received: 2011-04-02 Accepted : 2011-08-06 Published : 2011-03-20

Keywords: Determination, Thiosemicarbazide, Adsorptive stripping voltammetry, Real sample,

Abstract :

In the present work, an adsorptive stripping voltammetric method using a hanging mercurydrop electrode (HMDE) was described in order to determine the ultra trace of thiosemicarbazidein different real samples. The method is based on accumulation of thiosemicarbazide on mercuryelectrode. The potential was scanned to the negative direction and the differential pulse strippingvoltammograms were recorded. The instrumental and chemical parameters were optimized. Theoptimized conditions were obtained in pH of 10.0, accumulation potential of 0.00 mV,accumulation time of 60 s, scan rate of 80 mV s-1 and pulse height of 50 mV. The relationshipbetween the peak current versus concentration was linear over the range of 0.50-100.00 ng mL-1.The limits of detection were 0.03 ng mL-1 and the relative standard deviation at 5.00 and 50.00ng mL-1 of thiosemicarbazide ion were obtained 2.1 and 1.7%, respectively (n = 8).

References:

[1] R. Setnescu, C. Barcutean, S. Jipa, T. Setnescu, Polymer Degrad. Stability. 85 (2004) 997-1001.
[2] D. Kovala Demertzi, A. Domopoulou, M.A. Demertzis, A. Papageor-giou, D.X. West, Polyhedron. 16
(1977) 3625-3633.
[3] E. Bernejo, R. Carballo, A. Castineiras, R. Dominguez, A.E. Liberta, C. Maichle-Mossmer, M.M.
Salberg, D.X. West, Eur. J. Inorg. Chem. 6 (1999) 965-973.
[4] E.E. Ebenso, U.J. Ekpe, B.I. Ita, O.E. Offiong, U.J. Ibok, Mater. Chem. Phys. 60 (1999) 79-90.
[5] A.S. Fouda, L.H. Madkour, A.A. El-Shafei, A.H. El-Asklany, Mat.-Wiss. Werkstoff. Tech. 26 (1995)
342-346.
L. Hosseinzadeh & et al. / J. Iran. Chem. Res. 4 (2011) 177-185
185
[6] M.M. Singh, R.B. Rastogi, B.N. Upadhyay, M. Yadav, Mater. Chem. Phys. 80 (2003) 283-293.
[7] E. Khamis, M.A. Ameer, N.M. Al-Andis, G. Al-Senani, Corrosion. 56 (2000) 127-138.
[8] G. Al-Senani, E. Khamis, A.A. Ameer, Adsorption. Sci. Technol. 18 (2000) 177-194.
[9] G.F.S. Andrade, G.A. Micke, M.F.M. Tavares, M.L. A. Temperini, J. Raman Spectros. 35 (2004)
1034-1041.
[10] B.T. Gowda, D.S. Mahadevappa, Microchem. J. 28 (1983) 374-391.
[11] M.A. Karimi, H. Abdollahi, H. Karami, F. Banifatemeh, J. Chin. Chem. Soc. 55 (2008) 129-136.
[12] I. Pinto, B. S. Sherigara, H.V.K. Udupa, Analyst. 116 (1991) 285-289.
[13] D. Amin, B. Shaba, Analyst. 112 (1987) 1457-1458.
[14] M. Sarwar, M.A. Sabir, R.R. Iqbal, Zh. Anal. Khim. 47 (1992) 932-934.
[15] Y.S. Varma, I. Singh, B.S. Garg, R.P. Singh, J. Chin. Chem. Soc. 28 (1981) 169-171.
[16] A. Niazi, J. Ghasemi, M. Zendehdel, Talanta 74 (2007) 247-254.
[17] J. Ghasemi, A. Niazi, R. Ghorbani, Anal. Lett. 39 (2006) 1159-1169.
[18] A. Niazi, J. Chin. Chem. Soc. 54 (2007) 1195-1200.
[19] T.H. Li, Q.L. Zhao, M.H. Huang, Microchim. Acta 157 (2007) 245-249.
[20] A. Babaei, E. Shams, A. Samadzadeh, Anal. Sci. 22 (2006) 955-959.
[21] K. Zarei, M. Atabati, H. Ilkhani, Talanta 69 (2006) 816-821.
[22] M.B. Gholivand, A.A. Romiani, Anal. Chim. Acta 571 (2006) 99-104.
[23] R. Pirch, W.W. Kubiak, J. Electroanal. Chem. 599 (2007) 59-64.
[24] S. Abbasi, H. Khani, R. Tabaraki, Food Chem. 123 (2010) 507-512.
[25] A.A. Ensafi, T. Khayamian, A. Benvidi, E. Mirmomtaz, Anal. Chim. Acta. 561 (2006) 225-232.
[26] E. Laviron, J. Electroanal. Chem. 49 (1974) 395-402.
[27] A.P. Brown, F.A. Anson, Anal. Chem. 49 (1977) 1589-1594.
[28] L. Hosseinzadeh, S. Abbasi, H. Khani, Z. Khani, Transition. Met. Chem. 34 (2009) 425-431.