Selective oxidation of primary alcohols to aldehydes with H5IO6/V2O5 in ionic liquid

Subject Areas : Journal of the Iranian Chemical Research

Ming  Lu ¹ (Chemical Engineering College, Nanjing University of Sciece & Technology, Nanjing 210094, China)
Xiaobing  Liu ² (Chemical Engineering College, Nanjing University of Sciece & Technology, Nanjing 210094, China)
Yu  Wang ³ (Chemical Engineering College, Nanjing University of Sciece & Technology, Nanjing 210094, China)

Received: 2011-02-24 Accepted : 2011-07-15 Published : 2011-03-20

Keywords: Oxidation, Primary alcohol, aldehyde, Ionic liquid, catalyst,

Abstract :

An efficient protocol for the selective oxidation of primary alcohols to aldehydes withH5IO6/V2O5 in ionic liquid [bmpy][PF6] has been developed. High yields of the products, mildreaction conditions and simple experimental procedure make this protocol complementary tothe existing methods. The catalyst can be reused for several times without obvious loss of thecatalytic activity.

References:

[1] S. Venkatesan, A.S. Kumar, J.M. Zen, J. Mol. Catal. A 250 (2006) 87-93.
X. Liu & et al. / J. Iran. Chem. Res. 4 (2011) 135-139
139
[2] A.V. Biradar, M.K. Dongare, S.B. Umbarkar, Tetrahedron Lett. 50 (2009) 2885-2888.
[3] G. Bianchini, M. Crucianelli, F. de Angelis, V. Neri, R. Saladino, Tetrahedron Lett. 46 (2005) 2427-
2432.
[4] F.M. Menger, C. Lee, Tetrahedron Lett. 22 (1981) 1655-1656.
[5] C.K. Lee, B.S. Koo, Y.S. Lee, H. Cho, K.K. Lee, J. Bull. Korean Chem. Soc. 23 (2002) 1667-1670.
[6] R.A. Strecker, N.J. Randolph, US Pat. (1982) 4338442.
[7] K.R. Seddon, A. Stark, Green Chem. 4 (2002) 119-123.
[8] A. Wolfson, S. Wuyts, V.D. De, I.F.J. Vankelecom, P.A. Jacobs, Tetrahedron Lett. 43 (2002) 8107-
8110.
[9] B.S. Chhikara, S. Tehlan, A. Kumar, Synlett. (2005) 63-65.
[10] A. Kumar, N. Jain, S.M. Chauhan, Synlett. (2007) 411-414.
[11] N. Jiang, A.J. Ragauskas, J. Org. Chem. 71 (2006) 7087-7090.
[12] S.E. Martin, D.F. Suarez, Tetrahedron Lett. 43 (2002) 4475-4479.
[13] M. Saravanababu, J.L. Robert, Curr. Org. Synth. 2 (2005) 437-451.
[14] M.A.P. Martins, C.P. Frizzo, D.N. Moreira, N. Zanatta, H.G. Bonacorso, Chem. Rev. 108 (2008)
2015-2050.
[15] J. Muzart. Adv. Synth. Catal. 348 (2006) 275-295
[16] Y.L. Hu, X. Liu, M. Lu, H. Jiang. J. Chin. Chem. Soc. 57 (2010) 28-33.
[17] A. Butler, M.J. Clague, G.E. Meister, Chem. Rev. 94 (1994) 625-638.