بررسی فرآیندهای تصفیه پساب کاستیک دورریز پالایشگاه نفت بندرعباس
محورهای موضوعی :
آلودگی های محیط زیست (آب، خاک و هوا)
رقیه علمی
1
,
آرزو نجائی
2
,
امیر فرشی
3
,
محمد ابراهیم رمضانی
4
,
ابراهیم علایی
5
1 - دانشجوی دکتری محیط زیست، گروه محیط زیست، واحد تبریز، دانشگاه آزاد اسلامی، تبریز، ایران.
2 - استادیار، گروه محیط زیست، دانشگاه آزاد اسلامی، واحد تبریز، تبریز، ایران.
3 - استادیار، پژوهشگاه صنعت نفت (RIPI)، تهران، ایران.
4 - استادیار، گروه محیط زیست، واحد تبریز، دانشگاه آزاد اسلامی، تبریز، ایران.
5 - دانشیار، پژوهشگاه صنعت نفت (RIPI)، تهران، ایران.
تاریخ دریافت : 1400/03/13
تاریخ پذیرش : 1400/05/18
تاریخ انتشار : 1400/10/01
کلید واژه:
نمودار رویه پاسخ,
کاستیک,
COD,
باکس-بنکن,
اکسیداسیون هوای مرطوب,
چکیده مقاله :
زمینه و هدف: رهاسازی پساب‌های کاستیک دورریز واحدهای پالایشگاهی بدون اعمال روش‌های تصفیه به دلیل دارا بودن ترکیبات سمی فراوان و اکسیژن‌خواهی شیمیایی (COD) زیاد، آثار سوء محیط‌زیستی به دنبال دارد. در این پژوهش دو فرآیند اکسیداسیون هوای مرطوب (WAO) و خنثی‌سازی با اسید سولفوریک (DAN) به منظور تصفیه فاضلاب کاستیک دورریز پالایشگاه نفت بندرعباس در جنوب ایران مورد بررسی و بهینه‌سازی قرار گرفتند.روش بررسی: این فرآیندها در آزمایشگاه به ترتیب بوسیله‌ی یک راکتور شیشه‌ای و یک راکتور با حجم 500 میلی‌لیتر به صورت نیمه پیوسته، به مدت 18 ماه، از شهریور 1398 انجام شد. آزمایش‌های فرآیند تصفیه مربوط به دو روش بر روی تعدادی از فاکتورهای مهم انجام شد و برای بهینه‌سازی نتایج آزمایش‌ها از نرم‌افزارDesign Expert استفاده شد. برای طراحی آزمایش‌ها از روش باکس-بنکن (BBD) استفاده شد.یافته‌ها: نتایج حاکی از آن بود که فرآیند WAO کاهش 43 درصدی COD را نشان داده، پارامترهای دما و فشار، بیشترین تاثیر را در کاهش COD کاستیک دورریز داشته و فرآیند DAN موجب کاهش 68 درصدی COD گردیده و پارامترهای pH و دما بیشترین تاثیر را داشته‌اند.بحث و نتیجه‌گیری: فرآیند WAO روشی محیط‌زیست دوست‌تر بوده و فرآیند DAN به دلیل رایج بودن، آسانی انجام آزمایش‌ها، نیاز کمتر به تجهیزات و هزینه کمتر، پیشنهاد می‌گردد.
چکیده انگلیسی:
Background and Objective: Release of wastewater from spent caustic of refinery without the application of treatment methods will have adverse environmental effects due to its high toxic compounds and high chemical oxygen demand (COD). In this study, two processes of wet air oxidation (WAO) and neutralization with sulfuric acid (DAN) were investigated and optimized for treatment of wastewater from spent caustic of the Bandar Abbas oil refinery in southern Iran.Material and Methodology: These processes were performed in the laboratory by a glass reactor and a 500 ml semi-continuous reactor for 18 months, from September 2019, respectively. Treatment process experiments involving two methods were performed on a number of important factors. Design Expert software was used to optimize the test results and Box- Benken (BBD) method was used to design the experiments.Findings: The results showed that the WAO process showed 43% reduction in COD. Temperature and pressure parameters had the greatest impact on the reduction of spent caustic COD. The DAN process reduced the COD by 68%. pH and temperature parameters had the most impact.Discussion and Conclusion: WAO has been a more environmentally friendly method, and the DAN process is recommended because of its popularity, ease of testing, lower equipment requirements, and lower cost.
منابع و مأخذ:
Hasanzadegan Roudsari, M., Soltani, M., Seyedin, S.H., Chen, P., 2017. Investigation on New Method of Spent Caustic Treatment. Journal of Multidisciplinary Engineering Science and Technology (JMEST), 4(6): 7459- 7464.
Nasr Esfahani, K., Farhadian, M. and Nazar, A.S., 2019. Interaction effects of various reaction parameters on the treatment of sulfidic spent caustic through electro-photo-Fenton. International Journal of Environmental Science and Technology, 16(11): 7165-7174.
Ahmadpour, A., Haghighiasl, A. and Fallah, N., 2018. Investigation of spent caustic wastewater treatment through response surface methodology and artificial neural network in a photocatalytic reactor. Iranian Journal of Chemical Engineering (IJChE), 15(1): 46-72. (In Persian).
Haghighi Asl, A., Ahmadpour, A., Fallah, N., 2018. Modeling of Petrochemical industries wastewater COD Removal with DOE & ANN. Journal of modeling in engineering, 16 (54): 295-307. (In Persian)
Karimi, A., Savari, C., Bazyar, C., Rafiei, M., 2020. Study of Spent Caustic Wastewater Treatment Methods in Petrochemical Plants and Simulation of Optimum Process. Journal of Civil and Environmental Engineering, 50(3): 59-67. (In Persian)
Chen, C., and Cheng, T., 2013. Wet air oxidation and catalytic wet air oxidation for refinery spent caustics degradation. Journal of the Chemical Society of Pakistan, 35(2): 244-250.
Farzi, A. and Moslemi Byrami, S., 2015. Treatment of ethylene spent caustic pollutant using sulfuric acid. International Journal of Scientific & Engineering Research, 6(10): 382-386.
Barge, A.S. and Vaidya, P.D., 2018. Wet air oxidation of cresylic spent caustic–A model compound study over graphene oxide (GO) and ruthenium/GO catalysts. Journal of environmental management, 212: 479-489.
Alipour, Z. and Azari, A., 2020. COD removal from industrial spent caustic wastewater: A review. Journal of Environmental Chemical Engineering, 8(3), p.103678.
Pino-Cortés, E., Montalvo, S., Huiliñir, C., Cubillos, F. and Gacitúa, J., 2020. Characteristics and Treatment of Wastewater from the Mercaptan Oxidation Process: A Comprehensive Review. Processes, 8(4), p.425.
Samadiafshar, A., 2012. Study on basic methods of spent caustic treatment. In The first international conference oil, gas, petrochemical and power plant, University of Tehran, Tehran. 6pp. (In Persian)
Mortazavian, A., Mortaheb, H.R., and Mafi, M., 2018. Spent caustic wastewater treatment of petrochemical units by wet air oxidation process. Journal of Applied Research in Chemistry. 2: 59-67. (In Persian)
Arabian, D., A. Bolhasani and S. Karamian. 2018. Optimization of Spent caustic effluent treatment of Jam Petrochemical by wet air oxidation method. 5th International Conference On Recent Innovations in Chemistry and Chemical Engineering. 2 Feb. Tehran, Iran. 1-15. (In Persian)
Luan, M., Jing, G., Piao, Y., Liu, D. and Jin, L., 2012. Treatment of refractory organic pollutants in industrial wastewater by wet air oxidation. Arabian Journal of Chemistry, 10: S769-S776.
Karimi, A., Fatehifar, E., Alizadeh, R. and Ahadzadeh, I., 2016. Regeneration and treatment of sulfidic spent caustic using analytic hierarchy process. Environmental Health Engineering and Management Journal, 3(4): 203-208.
Kumari, M. and Saroha, A.K., 2018. Performance of various catalysts on treatment of refractory pollutants in industrial wastewater by catalytic wet air oxidation: A review. Journal of environmental management, 228: 169-188.
Hawari, A., Ramadan, H., Abu-Reesh, I. and Ouederni, M., 2015. A comparative study of the treatment of ethylene plant spent caustic by neutralization and classical and advanced oxidation. Journal of environmental management, 151: 105-112.
Ellis, C.E., Lawson, R.J., and Brandenburg, B.L., 1998. Wet Air Oxidation of Ethylene Plant Spent Caustic. Environmental Progress, 17(1): 28-30.
Mohammadizadeh, Z., Farshi, A., Royaee, S.J., and Jodaree, N., 2018. An Extensive Review On Spent Caustic Treatment Methods In Oil And Gas Industry. Iranian Chemical Engineering Journal, 17(96): 39-55. (In Persian)
Salimi, S., and Ovaysi, S., 2020. Spent caustic treatment of Kermanshah Oil Refining Company Using wet air oxidation method. 6th National Congress on Strategic Research in Chemical and Chemical Engineering with Emphasis on Iranian Native Technologies. 20 Jun, Tehran, Iran. 1-12. (In Persian)
Ketu, J., 2013. Treatment and disposal of spent caustic at TEMA oil refinery (TOR) (Doctoral dissertation).
Seyedin, S.H. and Hassanzadeganroudsari, M., 2018. The Efficient Process for Spent-caustic Wastewater Treatment. International Journal of Advanced Research in Science, Engineering and Technology, 5(2): 5284-5288.
Arena, F., Italiano, C., Raneri, A. and Saja, C., 2010. Mechanistic and kinetic insights into the wet air oxidation of phenol with oxygen (CWAO) by homogeneous and heterogeneous transition-metal catalysts. Applied Catalysis B: Environmental, 99(1-2): 321-328.
Padoley, K.V., Tembhekar, P.D., Saratchandra, T., Pandit, A.B., Pandey, R.A. and Mudliar, S.N., 2012. Wet air oxidation as a pretreatment option for selective biodegradability enhancement and biogas generation potential from complex effluent. Bioresource technology, 120: 157-164.
Rai, S., Wasewar, K.L., Lataye, D.H., Mishra, R.S., Puttewar, S.P., Chaddha, M.J., Mahindiran, P., and Mukhopadhyay, J., 2012. Neutralization of red mud with pickling waste liquor using Taguchi’s design of experimental methodology. Waste Management & Research, 30(9): 922–930.
Zhu, W., Bin, Y., Li, Z., Jiang, Z. and Yin, T., 2002. Application of catalytic wet air oxidation for the treatment of H-acid manufacturing process wastewater. Water Research, 36(8): 1947-1954.
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Hasanzadegan Roudsari, M., Soltani, M., Seyedin, S.H., Chen, P., 2017. Investigation on New Method of Spent Caustic Treatment. Journal of Multidisciplinary Engineering Science and Technology (JMEST), 4(6): 7459- 7464.
Nasr Esfahani, K., Farhadian, M. and Nazar, A.S., 2019. Interaction effects of various reaction parameters on the treatment of sulfidic spent caustic through electro-photo-Fenton. International Journal of Environmental Science and Technology, 16(11): 7165-7174.
Ahmadpour, A., Haghighiasl, A. and Fallah, N., 2018. Investigation of spent caustic wastewater treatment through response surface methodology and artificial neural network in a photocatalytic reactor. Iranian Journal of Chemical Engineering (IJChE), 15(1): 46-72. (In Persian).
Haghighi Asl, A., Ahmadpour, A., Fallah, N., 2018. Modeling of Petrochemical industries wastewater COD Removal with DOE & ANN. Journal of modeling in engineering, 16 (54): 295-307. (In Persian)
Karimi, A., Savari, C., Bazyar, C., Rafiei, M., 2020. Study of Spent Caustic Wastewater Treatment Methods in Petrochemical Plants and Simulation of Optimum Process. Journal of Civil and Environmental Engineering, 50(3): 59-67. (In Persian)
Chen, C., and Cheng, T., 2013. Wet air oxidation and catalytic wet air oxidation for refinery spent caustics degradation. Journal of the Chemical Society of Pakistan, 35(2): 244-250.
Farzi, A. and Moslemi Byrami, S., 2015. Treatment of ethylene spent caustic pollutant using sulfuric acid. International Journal of Scientific & Engineering Research, 6(10): 382-386.
Barge, A.S. and Vaidya, P.D., 2018. Wet air oxidation of cresylic spent caustic–A model compound study over graphene oxide (GO) and ruthenium/GO catalysts. Journal of environmental management, 212: 479-489.
Alipour, Z. and Azari, A., 2020. COD removal from industrial spent caustic wastewater: A review. Journal of Environmental Chemical Engineering, 8(3), p.103678.
Pino-Cortés, E., Montalvo, S., Huiliñir, C., Cubillos, F. and Gacitúa, J., 2020. Characteristics and Treatment of Wastewater from the Mercaptan Oxidation Process: A Comprehensive Review. Processes, 8(4), p.425.
Samadiafshar, A., 2012. Study on basic methods of spent caustic treatment. In The first international conference oil, gas, petrochemical and power plant, University of Tehran, Tehran. 6pp. (In Persian)
Mortazavian, A., Mortaheb, H.R., and Mafi, M., 2018. Spent caustic wastewater treatment of petrochemical units by wet air oxidation process. Journal of Applied Research in Chemistry. 2: 59-67. (In Persian)
Arabian, D., A. Bolhasani and S. Karamian. 2018. Optimization of Spent caustic effluent treatment of Jam Petrochemical by wet air oxidation method. 5th International Conference On Recent Innovations in Chemistry and Chemical Engineering. 2 Feb. Tehran, Iran. 1-15. (In Persian)
Luan, M., Jing, G., Piao, Y., Liu, D. and Jin, L., 2012. Treatment of refractory organic pollutants in industrial wastewater by wet air oxidation. Arabian Journal of Chemistry, 10: S769-S776.
Karimi, A., Fatehifar, E., Alizadeh, R. and Ahadzadeh, I., 2016. Regeneration and treatment of sulfidic spent caustic using analytic hierarchy process. Environmental Health Engineering and Management Journal, 3(4): 203-208.
Kumari, M. and Saroha, A.K., 2018. Performance of various catalysts on treatment of refractory pollutants in industrial wastewater by catalytic wet air oxidation: A review. Journal of environmental management, 228: 169-188.
Hawari, A., Ramadan, H., Abu-Reesh, I. and Ouederni, M., 2015. A comparative study of the treatment of ethylene plant spent caustic by neutralization and classical and advanced oxidation. Journal of environmental management, 151: 105-112.
Ellis, C.E., Lawson, R.J., and Brandenburg, B.L., 1998. Wet Air Oxidation of Ethylene Plant Spent Caustic. Environmental Progress, 17(1): 28-30.
Mohammadizadeh, Z., Farshi, A., Royaee, S.J., and Jodaree, N., 2018. An Extensive Review On Spent Caustic Treatment Methods In Oil And Gas Industry. Iranian Chemical Engineering Journal, 17(96): 39-55. (In Persian)
Salimi, S., and Ovaysi, S., 2020. Spent caustic treatment of Kermanshah Oil Refining Company Using wet air oxidation method. 6th National Congress on Strategic Research in Chemical and Chemical Engineering with Emphasis on Iranian Native Technologies. 20 Jun, Tehran, Iran. 1-12. (In Persian)
Ketu, J., 2013. Treatment and disposal of spent caustic at TEMA oil refinery (TOR) (Doctoral dissertation).
Seyedin, S.H. and Hassanzadeganroudsari, M., 2018. The Efficient Process for Spent-caustic Wastewater Treatment. International Journal of Advanced Research in Science, Engineering and Technology, 5(2): 5284-5288.
Arena, F., Italiano, C., Raneri, A. and Saja, C., 2010. Mechanistic and kinetic insights into the wet air oxidation of phenol with oxygen (CWAO) by homogeneous and heterogeneous transition-metal catalysts. Applied Catalysis B: Environmental, 99(1-2): 321-328.
Padoley, K.V., Tembhekar, P.D., Saratchandra, T., Pandit, A.B., Pandey, R.A. and Mudliar, S.N., 2012. Wet air oxidation as a pretreatment option for selective biodegradability enhancement and biogas generation potential from complex effluent. Bioresource technology, 120: 157-164.
Rai, S., Wasewar, K.L., Lataye, D.H., Mishra, R.S., Puttewar, S.P., Chaddha, M.J., Mahindiran, P., and Mukhopadhyay, J., 2012. Neutralization of red mud with pickling waste liquor using Taguchi’s design of experimental methodology. Waste Management & Research, 30(9): 922–930.
Zhu, W., Bin, Y., Li, Z., Jiang, Z. and Yin, T., 2002. Application of catalytic wet air oxidation for the treatment of H-acid manufacturing process wastewater. Water Research, 36(8): 1947-1954.
