• صفحه اصلی
  • بررسی فرایند ازن زنی کاتالیزوری با نانوکامپوزیت هیدروکسید لایه ای دوگانه منیزیم-آلومنیوم نشانده شده بر روی زئولیت در معدنی سازی آنتی بیوتیک سفکسیم در محیط آبی

اشتراک گذاری

آدرس مقاله


کد مقاله : JEST-2206-5709 (R2) بازدید : 70 صفحه: 29 - 47

10.30495/jest.2023.68268.5709

نوع مقاله: پژوهشی

بررسی فرایند ازن زنی کاتالیزوری با نانوکامپوزیت هیدروکسید لایه ای دوگانه منیزیم-آلومنیوم نشانده شده بر روی زئولیت در معدنی سازی آنتی بیوتیک سفکسیم در محیط آبی

محورهای موضوعی : آلودگی محیط زیست (آب و فاضلاب)

یلدا شیخ 1 (دانشجوی دکتری، گروه شیمی، واحد گرگان، دانشگاه آزاد اسلامی، گرگان، ایران.)
الهام تازیکه لمسکی 2 (دانشیار، گروه شیمی، واحد گرگان، دانشگاه آزاد اسلامی، گرگان، ایران. * (مسوول مکاتبات))
یوسف دادبان شهامت 3 (دانشیار، مرکز تحقیقات بهداشت محیط، گروه مهندسی بهداشت محیط، دانشکده بهداشت، دانشگاه علوم پزشکی گلستان، گرگان، ایران.)

تاریخ دریافت : 1401/04/06 تاریخ پذیرش : 1402/02/06 تاریخ انتشار : 1402/03/01

کلید واژه: آنتی بیوتیک سفکسیم, نانو کامپوزیت MgAl, LDH/Zeolite, ازن زنی کاتالیزوری, روش سطح پاسخ,

چکیده مقاله :

زمینه و هدف: امروزه یکی از مشکلات موجود در نظام های سلامت در دنیا، تجویز و یا مصرف بی رویه داروها است. در این میان، آنتی بیوتیک ها از اهمیت ویژه ای برخوردارند. آنتی بیوتیک ها گروهی از مواد دارویی هستند که به طور وسیعی در پزشکی و دامپزشکی مورد استفاده قرار گرفته اند. سفکسیم نیز یکی از این آنتی بیوتیک ها می باشد. هدف از این مطالعه، بررسی راندمان حذف سفکسیم از نمونه سنتتیک با استفاده از ازن زنی کاتالیزوری با هیدروکسید لایه ای دوگانه منیزیم- آلومنیوم نشانده شده بر زئولیت (MgAl-LDH/Zeolite) است. روش بررسی: در این مطالعه تجربی و آزمایشگاهی از نانو کامپوزیت MgAl-LDH/Zeolite در راکتور آزمایشگاهی و با استفاده از ازن زنی، جهت حذف سفکسیم استفاده گردید. اثر متغیرهای pH(5، 6، 7، 8، 9)، مقدار نانو کامپوزیت (5/0، 1، 5/1، 2، 5/2 گرم در لیتر) ، غلظت اولیه سفکسیم (5، 10، 15، 20، 25 میلی گرم در لیتر) و زمان ماند (5، 75/18، 5/32، 25/46، 60 دقیقه) برای یافتن حداکثر راندمان معدنی سازی مورد بررسی قرار گرفتند و جهت طراحی آزمایش ها، تجزیه تحلیل داده ها ودستیابی به شرایط بهینه از روش سطح پاسخ بر مبنای طراحی مرکب مرکزی (CCD) استفاده گردید. همچنین برای تجزیه و تحلیل داده ها از آنالیز واریانس استفاده شد. این تحقیق در سال 1401-1400 انجام گرفته است. یافته ها: حداکثر راندمان معدنی کردن سفکسیم در شرایط بهینه (pH 70/8، مقدار نانو کامپوزیت 76/1 گرم بر لیتر، غلظت اولیه سفکسیم 06/24میلی گرم بر لیتر و زمان تماس 76/40 دقیقه) 78 درصد می باشد، که با افزایش مقدار pH و زمان تماس راندمان حدف افزایش می یابد. بحث و نتیجه گیری: فرایند ازن زنی کاتالیزوری با نانو کامپوزیت هیدروکسید لایه ای دوگانه منیزیم- آلومنیوم نشانده شده بر زئولیت می تواند به طور موثر و کارآمدی برای حذف سفکسیم در محیط های آبی مورد استفاده قرار گیرد.

چکیده انگلیسی:

Background and Objective: One of the problems in the health systems of the world today is the prescription or overuse of drugs. Among these, antibiotics are of particular importance. Antibiotics are a group of drugs that are widely used in medicine and veterinary medicine. Cefixime (CFX) is also one of these antibiotics. The aim of this study was to investigate the removal efficiency of cefixime from synthetic sample using catalytic ozonation with Mg-Al layered double hydroxides Doped with zeolite. Material and Methodology: In this experimental and laboratory study MgAl-LDH/Zeolite nanocomposite was used in laboratory reactor and ozonation to remove cefixime. Effect of pH variables (5,6,7,8,9), amount of nanocomposite (0.5,1,1.5,2,2.5 g/L), initial concentration of cefixime (5,10,15,20,25 mg/L) and reaction time (5,18.75,32.5,46.25,60 min) were examined to find the maximum mineralization efficiency and response surface methodology based on central composite design (CCD) was used to design experiments, analyze data and achieve optimal conditions. Analysis of variance was also used to analyze the date. This research was done in 2021-2022. Findings: The maximum mineralization efficiency of cefixime under optimal conditions (pH=8.70, nanocomposite value=1.76 g/L, initial concentration of cefixime=24.06 mg/L, contact time=40.76 min) is 78%, which increases the target efficiency with increasing pH and contact time. Discussion and Conclusion: Catalytic ozonation process with Mg-Al layered double hydroxides nanocomposite Doped with zeolite can be used effectively and efficiency to remove cefixime in aqueous media.  

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  1. Githinji, LJ., Musey, MK., Ankumah, RO., 2011. Evaluation of the fate of ciprofloxacin and amoxicillin in domesticWater,Air,&SoilPollution,Vol.219,pp.191-201.
    2.
  2. Shemer, H., Kunukcu, YK., Linden, KG., 2006. Degradation of the pharmaceutical metronidazolevia UV, Fenton andphoto-Fenton processes. Chemosphere, Vol.63, pp. 269-276
    3.
  3. Mackuľak, T., Mosný, M., Grabic, R., Golovko, O., Koba, O., Birošová, L., 2015. Fenton-like reaction: a possible way to efficiently remove illicit drugs and pharmaceuticals from wastewater. Environ Toxicol Pharmacol, Vol.39, pp. 483-488.
    4.
  4. Asadi, Z., Ahmadi, S., 2019. Investigation of the efficiency of coagulation process for ciprofloxacin antibiotic removal from aqueous solution. J Health Res Community, Vol. 5, pp.38-48.
    5.
  5. Nasseh, N., Barikbin, B., Nasseri, M.A., 2016.  Antibiotics Pollution Damaging Effects on Environment and Review of Efficiency of Different Methods for Removing them.  Nurse and Physician within War,Vol.4, pp.50-62. (In Persian)
    6.
  6. Mostafaloo, R., Mahmoudian, MH., Asadi-Ghallhari, , 2019. BiFeO-3/Magnetic nanocomposites for thephotocatalytic degradation of cefixime from aqueoussolutions under visible light. Photochem PhotobiolA Chem, Vol. 382, pp.111926.
    7.
  7. Khan, MN., Qayum, A., Rehman, UU., Guulab, H., Idrees, , 2015. Spectrophotometric method for quantitativedetermination of cefixime in buik and pharmaceuticalpreparation using ferroin complex. Appl Spectrosc, Vol.82,pp.705-711.
    8.
  8. Maheshwari, M., Memon, A., Memon, S., Mughal,, Dayo, A., Memon, N., 2015. Optimization ofHPLC method for determination of cefixime using2-thiophenecarboxaldehyde as derivatizing reagent. Saudi Pharm,Vol. 23,pp.444-452.
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    20.
  20. Kermani, M., Farzadkia, M., Esrafili, A., Fallah Jokandan, S.,Yeganeh Badi, M., 2016. Removal of catechol from aqueoussolutions using catalytic ozonation by magneticnanoparticles of iron oxide doped with silica and titaniumdioxide: a kinetic study. Mazandaran U Med Sci,26,pp.139-154. (In Persian)
    21.
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    22.
  22. Lv, L., He, J., Wei, M., Evans, D., Duan, X., 2006. Factors influencing the removal of fluoride fromaqueous solution by calcined Mg–Al–CO3layered double hydroxides. Journal ofHazardous Materials,Vol 133, pp. 119-128.
    23.
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