Removal of Amoxicillin from Aqueous Solutions by using Synthesized Highly Hydrogel Surface as a Good Adsorbent

Subject Areas : Journal of Chemical Health Risks

Ibrahim J.  Sahib ¹ (College of Dentistry, University of Alkafeel, Najaf, Iraq)
Aseel  M. Aljeboree ² (Department of Chemistry, College of Sciences for Girls, University of Babylon, Hilla, Iraq)
Samaa M.  Hassan ³ (Ministry of Education, Directorate of Education, Babylon, Iraq)
Layth S.  Jasim ⁴ (Department of Pharmacology, College of Pharmacy, Al Farahidi University, Iraq)
Shahad M.  Qasim ⁵ (Department of Pharmacology, College of Pharmacy, Al Farahidi University, Iraq|Department of Chemistry, College of Education, University of Al-Qadisiyah, Diwaniya, Iraq)
AyadAyad  F. Alkaim ⁶ (Department of Chemistry, College of Sciences for Girls, University of Babylon, Hilla, Iraq)

Received: 2021-09-25 Accepted : 2022-01-05 Published : 2023-03-01

Keywords: Adsorption, Isotherm, Removal, Kinetic Model, Amoxicillin AMX drug,

Abstract :

Because of the potential for reversible effects on living organisms and bacterial elaboration resistance, removing drugs from aqueous solutions is critical. Deals with the amoxicillin AMX removal trial using hydrogel. (F-TIR), (F.E-SEM), and UV-visible spectroscopy were used to describe the hydrogel of sodium alginate-g-poly (Acrylic acid-fumaric acid). The purpose of the adsorption investigation was to determine the impact of (10-100 mg L-1) conc. of AMX Optimization appear to have the best percentage percent removal at 97.40 percent at concentration 100 mg L-1, and contact duration 2hr. Take a look at two isotherm models. The second order model (R2= 0.9041) outperforms the Freundlich, Langmuir (R2= 0.9772), and three types of kinetic models (first order, second order, and Elchovich).

References:

1. Layth S., J Aljeboree M.A., 2021. Removal of Heavy Metals by Using Chitosan/ Poly (Acryl Amide-Acrylic Acid)Hydrogels: Characterization and Kinetic Study . Neuro Quantology. 19(2), 31-37.


2. Yahya A., Faleh N.D.R., 2021. Removal of Metformin hydrochloride from Aqueous Solutions by using Carboxymethyl cellulose-g-poly (acrylic acid-co-acrylamide) Hydrogel: Adsorption and Thermodynamic Studies. IOP Conf. Series: Earth and Environmental Science. 790, 012062.

3.Wenyan Jiang L.Z., Xiaoming G., Mei Y., Yiwen L., Yijun W., Yousen Zh., Guangtao W., 2019. Adsorption of cationic dye from water using an iron oxide/activated carbon magnetic composites prepared from sugarcane bagasse by microwave method. Environmental Technology. 2. DOI: 10.1080/09593330.

4. Santos S.C.R.O., Boaventura A.F.M., 2019. Bentonitic clay as adsorbent for the decolourisation of dyehouse effluents. J Clean Prod. 126, 667-67.


5. Sakin O.A., Belal H.M., Arbi H.M., 2019. Adsorption thermodynamics of cationic dyes (methylene blue and crystal violet) to a natural clay mineral from aqueous solution between 293.15 and 323.15 K. Arabian Journal of Chemistry. 11(5), 615-623.


6. Israa M., Radhi F.H.A., Takialdin A., 2019. Himdan Influence of water in size of Synthesized Carbon Black Nanoparticles from Kerosene by Flame Method. IOP Conf. Series: Materials Science and Engineering. 571.


7. Aljeboree A.M., 2019. Colorimetric determination of Amoxicillin using 4-Aminoantipyrine and the effects of different parameters. Journal of Physics: Conference Series. 12(5), 052067.


8. Aljeboree A.M., 2019. Comparative removal of three textile dyes from aqueous solutions by adsorption: as a model (corn-cob source waste) of plants role in environmental enhancement. Plant Archives. 19(1), 1613-1620.


9. Aljeboree A.M., Alshirifi A.N., 2019. Oxidative coupling of Amoxicillin using 4-Aminoantipyrine: Stability and higher sensitivity. Journal of Physics: Conference Series. 1294(5), 052001.


10. Aljeboree A.M, Alshirifi A.N.A., 2019. Determination of Phenylephrine Hydrochloride and Amoxicillin in a Binary Mixture using Derivative Spectrophotometry Methods. International Journal of Pharmaceutical Quality Assurance. 10(3), 168-177.


11. Aljeboree A.M., Abbas A.S., 2019. Removal of Pharmaceutical (Paracetamol) by using CNT/ TiO₂ Nanoparticles. Journal of Global Pharma Technology. 11(1), 199-205.


12. Firas H., Abdulrazzak A.M.A., Tariq H. Al M., Israa M., Ajobree A.M., Ayad F.A.,Takialdin A. H., Falah H.H., 2020. Novel Coronavirus 2019-nCoV Selectivity and Activity between Asians and Europeans Populations: A Review. International Journal of Psychosocial Rehabilitation. 24(5), 2829-2837.


13. Liqaa H., Abd R.A., Aljeboree Aseel M., Firas H., Abdulrazzak Falah H.H., Ayad F. A., 2019. Role of Semiconductors (Zinc Oxide as a Model) for Removal of Pharmaceutical Tetracycline (TCs) from Aqueous Solutions in the Presence of Selective Light. International Journal of Recent Technology and Engineering (IJRTE). 8(2S3). DOI : 10.35940/ijrte.B1270.0782S319.


14. Doğan M., Alkan M., Demirbas O., Ozdemir Y., Ozmetin C., 2006. Adsorption kinetics of maxilon blue GRL onto sepiolite from aqueous solutions. Chem Eng J. 124, 89-101.


15. Ahmad R., 2009. Studies on adsorption of crystal violet dye from aqueous solution onto coniferous pinus bark powder (CPBP). J Hazard Mater. 171, 767-773.


16. Abdulrazzak F.H., 2016. Enhance photocatalytic Activity of TiO₂ by Carbon Nanotubes. International Journal of Chem Tech Research. 9(3), 431-443

17.Ayad F., Alkalim M.B.A., 2013. Adsorption of basic yellow dye from aqueous solutions by activated carbon derived  from waste apricot stones (ASAC): equibrium , and thermodynamic aspects. Int J Chem Sci. 11(2), 797-814.

18. Ali M., Jassm B.A.J., Firas H., Abdulrazzak A., Alkaim F., Falah H.H., 2017. Synthesis and Characterization of Carbon Nanotubes by Modified Flame Fragments Deposition Method. Asian Journal of Chemistry. 29(12), 2804-2808.


19. Ayad F. Alkaim, A.M.A., 2020. White Marble as an Alternative Surface for Removal of Toxic Dyes (Methylene Blue) from Aqueous Solutions. International Journal of Advanced Science and Technology. 29(5), 5470 - 5479.


20. Aljeboree A.M., 2019. Adsorption and Removal of pharmaceutical Riboflavin (RF) by Rice husks Activated Carbon. International Journal of Pharmaceutical Research. 11(2), 255-261.


21. Abdulsahib W.K., Ganduh S.H., Mahdi M.A., Jasim L.S., 2020. Adsorptive removal of doxycycline from aqueous solution using graphene oxide/hydrogel composite. International Journal of Applied Pharmaceutics. 12(6), 100-106.


22. Nandi B.K., Purkait M.K., 2009. Adsorption characteristics of brilliant green dye on kaolin. J Hazard Mater. 161, 387-395.


23. Ahmed M.J., 2017. Adsorption of quinolone, tetracycline, and penicillin antibiotics from aqueous solution using activated carbons: Review. Environmental Toxicology and Pharmacology. 50, 1-10.


24. Crini G., Peindy H.N., Gimbert F., Robert C., 2007. Removal of C.I. basic green 4, (malachite green) from aqueous solutions by adsorption using cyclodextrin-based adsorbent: kinetic and equilibrium studies. Purif Technol. 53, 97-110.


25. Ho Y.S., Porter J.F., McKay G., 2002. Individual response profiles of male Wistar rats in animal models for anxiety and depression. Water Air Soil Pollut. 141, p. 1-12.


26. Özacar M., Şengil İ.A., 2003. Adsorption of reactive dyes on calcined alunite from aqueous solutions. J Hazard Mater. B98, 211–224.


27. Langmuir I., 1916. The constitution and fundamental properties of solides and liquids. Part I. Solids J Am Chem Soc. 38(11), 2221-2295.


28. Langmuir I., 1918. The adsoption of gases on plane surfaces of glass, Mica and platinum. J Am Chem Soc. 40(9), 1361–1403.


29. Freundlich H.W., 1939. The Adsorption of cis- and trans-Azobenzene. J Am Chem Soc. 61, 2228-2230.

30.Ho Y.S., McKay G., 1998. Orption of dye from aqueous solution by peat. S Chem Eng J. 70, 115.