The Removing Cadmium Ions from Aqueous Solutions Using Barley Straw: An Experimental Study
Subject Areas :
Journal of Chemical Health Risks
Maysam Salih Mutlaq
1
,
Mohammed Azwaz
2
,
Nahed Mahmood Ahmed
3
,
Ashour H. Dawood
4
,
Alaa A. Omran
5
,
Rana Warid Maya
6
,
Talib Kh. Hussein
7
,
Hind Ali Nasser
8
1 - Department of Pharmacy, Al-Noor University College, Nineveh, Iraq
2 - Department of Medical Instruments Engineering Techniques, Al-Farahidi University, Baghdad, Iraq
3 - College of Pharmacy, National University of Science and Technology, Dhi Qar, Iraq
4 - Department of Medical Engineering, Al-Esraa University College, Baghdad, Iraq
5 - Department of Medical Engineering, AL-Nisour University College, Baghdad, Iraq
6 - Department of Medical Engineering, Mazaya University College, Iraq
7 - Department of Medical Engineering, Al-Hadi University College, Baghdad, 10011, Iraq
8 - College of pharmacy, Al-Ayen University, Thi-Qar / Iraq
Received: 2023-08-03
Accepted : 2023-11-19
Published : 2024-03-16
Keywords:
Toxicity,
Cadmium,
barley straw,
FTIR analysis,
Abstract :
Cadmium is a toxic metal that can contaminate water sources and pose serious health risks to humans and the environment. Therefore, there is a need for developing low-cost and eco-friendly methods for cadmium removal from water. In this research, we investigated the efficacy of barley straw in removing cadmium ions from aqueous solutions. The adsorbent utilized was laboratory-scaled barley straw that underwent pulverization via standard ASTM sieves, specifically those within the 40 to 120-mesh sieve size range. The functionalization of barley straw was achieved via treatment with a 0.8 M NaOH solution. The adsorbent was subsequently characterized by FTIR analysis to identify the presence of functional groups. The FTIR analysis indicated that the modification of barley straw led to an elevation in the stretch vibration band of hydroxyl and carboxyl groups. At the optimized experimental condition, a cadmium removal efficiency of up to 98.60% was achieved. These results demonstrate the potential of barley straw as an effective adsorbent for removing cadmium ions from aqueous solutions.
References:
Jyothi N.R., 2020. Heavy Metal Sources and Their Effects on Human Health. IntechOpen. doi: 10.5772/intechopen.95370
Javidan P., Baghdadi M., Torabian A., Goharrizi B. A., 2022. A tailored metal–organic framework applicable at natural pH for the removal of 17α-ethinylestradiol from surface water. Cancer. 11, 13.
Tajfar I., Pazoki M., Pazoki A., Nejatian N., Amiri M., 2023. Analysis of Heating Value of Hydro-Char Produced by Hydrothermal Carbonization of Cigarette Butts. Pollution. 9(3), 1273-1280.
Farhan A.S., Jasim S.T., 2020. Cadmium Toxicity and some Target Organs: A Review. Al-Anbar J of Veter Sci. 13(2), 17–26.
Uddin M.M., Zakeel M.C.M., Zavahir J.S., Marikar F.M., Jahan I., 2021. Heavy metal accumulation in rice and aquatic plants used as human food: A general review. Toxics. 9(12), 360.
Ebrahimi M., Khalili N., Razi S., Keshavarz-Fathi M., Khalili N., Rezaei N., 2020. Effects of lead and cadmium on the immune system and cancer progression. Journal of Environmental Health Science and Engineering. 18 335–343.
Wang M., Chen Z., Song W., Hong D., Huang L., Li Y., 2021. A review on cadmium exposure in the population and intervention strategies against cadmium toxicity. Bulletin of Environmental Contamination and Toxicology. 106 65–74.
Li H., Wallin M., Barregard L., Sallsten G., Lundh T., Ohlsson C., Mellström D., Andersson E.M., 2020. Smoking-induced risk of osteoporosis is partly mediated by cadmium from tobacco smoke: The MrOS Sweden Study. Journal of Bone and Mineral Research. 35(8), 1424–1429.
Abad S.S.A.M.K., Javidan P., Baghdadi M., Mehrdadi N., 2023. Green synthesis of Pd@ biochar using the extract and biochar of corn-husk wastes for electrochemical Cr (VI) reduction in plating wastewater. Journal of Environmental Chemical Engineering. 11(3), 109911.
Mulware S.J., 2020. Toxicity of Heavy Metals, A. Subject in Review. International Journal of Recent Research in Physics and Chemical Sciences. 6(2), 30–43.
Rockey N.C., Shen Y., Haig S.J., Wax M., Yonts J., Wigginton K.R., Raskin L., Olson T.M., 2021. Impact of service line replacement on lead, cadmium, and other drinking water quality parameters in Flint, Michigan. Environmental Science: Water Research & Technology. 7(4), 797–808.
Vardhan K.H., Kumar P.S., Panda R.C., 2019. A review on heavy metal pollution, toxicity and remedial measures: Current trends and future perspectives. Journal of Molecular Liquids. 290, 111197.
Tofighy M.A., Mohammadi T., 2020. Divalent heavy metal ions removal from contaminated water using positively charged membrane prepared from a new carbon nanomaterial and HPEI. Chemical Engineering Journal. 388, 124192.
Saeidi S., Enjedani S.N., Behineh E.A., Tehranian K., Jazayerifar S., 2023. Factors Affecting Public Transportation Use during Pandemic: An Integrated Approach of Technology Acceptance Model and Theory of Planned Behavior. Tehnički Glasnik. 18(3), 1-12
Malik L.A., Bashir A., Qureashi A., Pandith A.H., 2019. Detection and removal of heavy metal ions: a review. Environmental Chemistry Letters. 17, 1495–1521.
Liu L., Li W., Song W., Guo M., 2018. Remediation techniques for heavy metal-contaminated soils: Principles and applicability. Science of the Total Environment. 633, 206–219.
Bolisetty S., Peydayesh M., Mezzenga R., 2019. Sustainable technologies for water purification from heavy metals: review and analysis. Chemical Society Reviews. 48(2), 463–487.
Fayazi M., 2019. Facile hydrothermal synthesis of magnetic sepiolite clay for removal of Pb (II) from aqueous solutions. Analytical and Bioanalytical Chemistry Research. 6(1), 125–136.
Flores M.I., Bravo-Thais S.C., Romero M.B., Guzman M.G., 2023. Evaluation of Heavy Metal Removal Using Phragmites Australis (Cav.) and Schoenoplectus Californicus (CA Mey.): A Comparison of the Dry Ashing and Wet Digestion Method. Analytical and Bioanalytical Chemistry Research. 10(1), 97–109.
Tsade H., Murthy H.A., Muniswamy D., 2020. Bio-sorbents from agricultural wastes for eradication of heavy metals: a review. J Mater Environ Sci. 11 1719–1735.
Ogunlalu O., Oyekunle I.P., Iwuozor K.O., Aderibigbe A.D., Emenike E.C., 2021. Trends in the mitigation of heavy metal ions from aqueous solutions using unmodified and chemically-modified agricultural waste adsorbents. Current Research in Green and Sustainable Chemistry. 4, 100188.
Ibisi N.E., Asoluka C.A., 2018. Use of agro-waste (Musa paradisiaca peels) as a sustainable biosorbent for toxic metal ions removal from contaminated water. Chem Int. 4(1), 52.
Ziarati P., Zahirnejad M., Asgar Pahanh J., 2017. The efficiency of bio-adsorption of heavy metals from pharmaceutical effluent by Rumex crispus L. Seed. Journal of Pharmaceutical & Health Sciences. 5(3), 231–243.
Priyadarshanee M., Das S., 2021. Biosorption and removal of toxic heavy metals by metal tolerating bacteria for bioremediation of metal contamination: A comprehensive review. Journal of Environmental Chemical Engineering. 9(1), 104686.
Imran-Shaukat M., Wahi R., Ngaini Z., 2022. The application of agricultural wastes for heavy metals adsorption: A meta-analysis of recent studies. Bioresource Technology Reports. 17, 100902.
Zhou Y., Zhang L., Cheng Z., 2015. Removal of organic pollutants from aqueous solution using agricultural wastes: a review. Journal of Molecular Liquids. 212, 739–762.
Kaikake K., Hoaki K., Sunada H., Dhakal R.P., Baba Y., 2007. Removal characteristics of metal ions using degreased coffee beans: Adsorption equilibrium of cadmium (II). Bioresource Technology. 98(15), 2787–2791.
Wang F.Y., Wang H., Ma J.W., 2010. Adsorption of cadmium (II) ions from aqueous solution by a new low-cost adsorbent—Bamboo charcoal. Journal of Hazardous Materials. 177(1–3), 300–306.
Bekri-Abbes I., Bayoudh S., Baklouti M., 2006. Converting waste polystyrene into adsorbent: potential use in the removal of lead and cadmium ions from aqueous solution. Journal of Polymers and the Environment. 14(3), 249–256.
Zarif Gharaati Oftadeh B., Tavakoly Sany B., Alidadi H., Zangouei M., Barati R., Naseri A., Tafaghodi M., 2021. Heavy Metals Contamination and Distribution in Drinking Water from Urban Area of Mashhad City in Northeast Iran: Implications for Water Quality Assessment. Journal of Chemical Health Risks. 11(4), 403–418.
Pirhadi M., Shariatifar N., Bahmani M., Manouchehri A., 2022. Heavy metals in wheat grain and its impact on human health: A mini-review. Journal of Chemical Health Risks. 12(3), 421–426.
Ince M., Ince O.K., Yonten V., Karaaslan N.M., 2016. Nickel, lead, and cadmium removal using a low-cost adsorbent-banana peel. At Spectrosc. 37(3), 125–130.