Adsorption of Erythrosine and Red Carmosine dyes from aqueous solutions with CuO adsorbent: kinetic and thermodynamic study

Subject Areas :

Nima Razzaghi-Asl ¹ (Department of Medicinal Chemistry, Ardabail Universtity of Medical Sciences , Ardabil , Iran)
Parya Nasehi ² (Department of Chemistry, Ahvaz Branch, Islamic Azad University, Ahvaz, Iran)

Received: 2016-01-03 Accepted : 2016-04-06 Published : 2016-06-01

Keywords: absorption, Copper oxide, Erythrosine, Red carmoisine,

Abstract :

In this study, Copper oxide as a good and inexpensive adsorbent has been introduced and used for the removal of erythrosine and red carmoisine dyes from several water solutions successfully. The effect of various parameters such as pH, dye concentration, amount of adsorbent, contact time and temperature on removal processing was investigated. Adsorption isothermal data could be interpreted by the Langmuir and Freundlich, isotherm models.

References:

[1] P. Grau, Water Sci . Technol. 24(1) (1991) 97.

[2] A.G. Tarek . K. shigeru . S. shigeo. K. Toshinori.Treatmentof synthetic dyes wastewater utilizing a magnetically separable photocatalyst (TiO₂/SiO₂/Fe₃O₄) : Parametric and kinetic studies Desalination 244 (1-3) (2009) 1-11.

[3] Y. Bulut.N. Gozubenli . H. Aydm.Equilibrium and kinetic studies for adsorption of direct blue 71from aqueous solution by wheat shells. J. Hszard . Mater. 144 (1-2) (2007) 300-306.

[4] Z.K. George .K. L. Nikolasos,Reactive and basic dyes removal by sorption on to chitosan derivatives J. Colloid Interface Sci. 331(1) (2009) 32-39.

[5] V.J.P. Poots, G. McKay, The specific surfaces of Peat and Wood, J. Appl. Polym. Sci. 23 (1979) 1117–1129.

[6] Yahya S. Al-Degs, Rajb Abu-El- Halawa, Samer S. Abu-Alrub, Analyzing adsorption data of erythrosine dye using principal component, Chemical Engineering Journal 191 (2012) 185-194.

[7] T. J. Ma , G. F. Yang, New Edition Handbook ofF ood Additives, Chinese Agriculture Publishing Press, Beijing 1989, pp 320-328.

[8] H. Tsuji . F . Yagi. H. Hattori .H. Kita. Self- Condensation of N-butylaldehyde over solid base Catalysis Journal of catalysis 148 (1994) 759-770.

[9] B. Van der Bruggen, C. Vandecasteele, Removal of pollutants from surface water and groundwater by nanofiltration: overview of possible applications in the drinking water industry, Environ. Pollut. 122 (2003) 435–445.

[10] P.C. Singer, Humic substances as precursors for potentially harmful disinfection by-products, Water Sci. Technol. 40 (1999) 25–30.

[11] D.B. Mosqueda-Jimenez, P.M. Huck, Effect of biofiltration as pretreatment on the fouling of nanofiltration membranes, Desalination 245 (2009) 60–72.

[12] F. Gottschalk, T. Sonderer, R.W. Scholz, B. Nowack, Modeled environmental

concentrations of engineered nanomaterials (TiO2, ZnO, Ag, CNT, fullerenes) for

different regions, Environ. Sci. Technol. 43 (2009) 9216–9222.

[13] Rajoriya, R.K., Prasad, B., Mishra, I..M., Wasewar, K.L. Adsorption of Benzaldehyde on Granular Activated Carbon: Kinetics, equilibrium, and Thermodynamics. Chem. Biochem. Eng. Q. 21 (2007), 221-224.

[14] Ng, C., Losso, J.N., Marshall, W.E., Rao, R.M. Freundlich adsorption isotherms of agricultural by-product-based powdered activated carbons in a geosmin-water system. Bioreso. Techno. 85 (2002), 131-133.

[15] Namasivayam, C., Arasi, D.J.S.E. Removal of Congo Red from wastewater by adsorption onto waste red mud. Chemo. 34 (1997), 407-413.

[16] H. Tang, C. Chang, L. Zhang, Efficient adsorption of Hg2+ ions on chitin/cellulose composite membranes prepared via environmentally friendly pathway, Chem. Eng. J. 173 (2011) 689–697.

[17] X. Hu, J. Wang, Y. Liu, X. Li, G. Zeng, Z. Bao, X. Zeng, A. Chen, F. Long, Adsorption of chromium (VI) by ethylenediamine-modified cross-linked magnetic chitosan resin: isotherms, kinetics and thermodynamics, J. Hazard. Mater. 185 (2011) 306–314.

[18] B. Samiey, A.R. Toosi, Adsorption of malachite green on silica gel: effects of

NaCl, pH and 2-propanol, J. Hazard. Mater. 184 (2010) 739–745.

[19] X. Bai, Z. Ye, Y. Li, L. Zhou, L. Yang, Preparation of crosslinked macroporous PVA foam carrier for immobilization of microorganisms, Process Biochem. 45 (2010) 60–66.

[20] L. Jin, R. Bai, Mechanisms of lead adsorption on chitosan/PVA hydrogel beads, Langmuir 18 (2002) 9765–9770.