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Manuscript ID : IJES-2108-1639 (R3) Visit : 388 Page: 248 - 263

10.30495/ijes.2023.1936911.1639

Article Type: Original Research

The petrology and geochemistry of Sorkheh-Dizaj intrusive rocks in northern Zanjan and its effects on recovery of LREE from tailingby digestion-water leaching processes, Iran

Subject Areas : Petrology

Ahmad Adib 1 , Esmaeil Rahimi 2

1 - Department of Petroleum and Mining Engineering, South Tehran Branch, Islamic Azad University, Tehran, Iran.
2 - Department of Petroleum and Mining Engineering, South Tehran Branch, Islamic Azad University, Tehran, Iran.

Received: 2022-12-18 Accepted : 2023-06-02 Published : 2023-10-01

Keywords: LREE, digest- water leaching, Morvarid Mine, Acid leaching,

Abstract :

Magnetite-apatite mineralization in Tarom Mountains at the western part of Alborz-Azerbaijan belt originated from quartz monzonite magma and belongs to high K calc-alkaline, showing a post-collision tectonic environment. The negative trend from LREEs to HREEs is consistent with the spider pattern of the subduction areas. In this article, the recovery of the rare-earth elements (REEs) from apatite flotation concentrate by acid leaching and digestion-water leaching were studied. The total amount of LREEs in the tailings sample is between 1500 - 2600 ppm. The most frequent elements are Ce, La, Nd, and Y. Among them Ce is the most abundant and La is the least.. The maximum LREEs recovery with the sulfuric acid leaching was62% with experimental parameters of 12 M acid concentration, 4 h leaching time, 25℃ heat, and a liquid to solid ratio (L/S) of 1:5. under optimal parameters of (220℃), (3 h), and L/S (1:2), the digesting with sulfuric acid resulted to the recovery of La, Ce, Nd, and Y with 93.92%, 92.22%, 92.04%, and 91.00%, respectively. similarity, the best conditions at water leaching process, are the leaching time of 5 h, at 80℃, and L/S of 1:10 for La, Ce, Nd, and Y recovery are respectively 89.50%, 88.45%, 92.20%, and 94.0%.

References:


  1. Adib A, Ahmadi R, Rahimi E (2021b) The Recovery of Rare-Earth Elements from Apatite concentrate by Acid and Digestion-Water Leaching Processes in Morvarid iron Mine, Iran. Journal of Mining Science 57:131-43.
    2.
  2. Adib A, Nabilou M, Afzal P (2021a) Relationship between Fe-Cu-REEs mineralization and magnetic basement faults using multifractal modeling in Tarom region, NW Iran. Episodes Episodes Journal of International Geoscience 1;45(3):223-37.
    3.
  3. Aly MM, Mohammed NA (1999) Recovery of lanthanides from Abu Tartur phosphate rock, Egypt. Hydrometallurgy 52: 199–206.
    4.
  4. Azimi G, Papangelakis VG (2010) The Solubility of gypsum and anhydrite in simulated laterite pressure acid leach solutions up to 250˝C. Hydrometallurgy 102: 1–13.
    5.
  5. Azizi H, Mehrabi B and Akbarpour A (2009) Genesis of Tertiary Magnetite–Apatite Deposits, Southeast of Zanjan, Iran, Resource Geology 59(4):330-41.
    6.
  6. Baratian M, Arian MA, Yazdi A (2018) Petrology and petrogenesis of the SiahKuh intrusive Massive in the South of KhoshYeilagh, Amazonia Investiga 7 (17): 616-629.
    7.
  7. Chappell BW, White AJR (1992) I- and S-type granites in the Lachlan Fold Belt. Transactions of the Royal Society of Edinburgh, Earth Sciences 83: 1-26.
    8.
  8. Chi R,  Tian J,  Zhu G, Wu Y,  Li S, Wang C,   Zhou ZA (2006) Kinetics of rare earth leaching from a manganese-removed weathered rare-earth mud in hydrochloric acid solutions. Separation Science and Technology 41: 1099–1113.
    9.
  9. Cox KG, Bell JD, Pankhurst RJ (1979) the interpretation of igneous rocks. George, Allen and Unwin, London.
    10.
  10. Davoudian AR, Genser J, Dachs E, Shabanian N (2008) Petrology of eclogites  from north of Shahrekord, Sanandaj-Sirjan zone, Iran. Mineralogy and Petrology 92: 393-413.
    11.
  11. Debon F, Le Fort P (1988) A cationic classification of common plutonic rocks and their magmatic associations: principles, method, applications. Bulletin de Minéralogie 111: 493–510.
    12.
  12. El-Nadi Y, El-Hefny NE, Aly HF (2013) Solvent extraction and recovery of Y(III) and Yb(III) from fluorspar mineral. Internarial journal of minerals, Metallurgy and Materials 20: 713-719.
    13.
  13. Frost, B. R., Barnes, C. G., Collins, W. J., Arculus, R. J., Ellis, D. J. & Frost, C. D. (2001). A geochemical classification for granitic rocks. Journal of Petrology 42: 2033–2048.
    14.
  14. Gharib-Gorgani F, Ashja-Ardalan A, Espahbod MR, Sheikhzakariaee SJ, Yazdi A (2017) Petrology of Mg-bearing Meta Ophiolite Complexes of Qaen-Gazik, Eastern Iran, National Cave Research and Protection Organization 4(1): 1-6.
    15.
  15. Ghasemi A, Talbot CJ (2006) A new tectonic scenario for the Sanandaj-Sirjan Zone (Iran). Journal of Asian Earth Sciences 26: 683-693.
    16.
  16. Golonka J (2004) Plate tectonic evolution of the southern margin of Eurasia in the Mesozoic and Cenozoic. Tectonophysics 381: 235-273.
    17.
  17. Gupta CK (1990) Hydrometallurgy in Extraction processes, Wiley-VCH.
    18.
  18. Gupta CK, Krishnamurthy N.(2005) Extractive Metallurgy of Rare Earths, CRC, Press, Florida.
    19.
  19. Hassanzadeh J, Ghazi AM, Axen G, Guest B (2002) Oligomiocene mafic-alkaline magmatism north and northwest of Iran: evidence for the separation of the Alborz from the Urumieh–Dokhtar magmatic arc. Geological Society of America Abstracts with Programs 34: 331.
    20.
  20. Henderson P (1984) Rare earth element geochemistry. Developments in geochemistry, 2. Elsevier, Amsterdam.
    21.
  21. Hu Z, Qi L (2014) Sample Digestion Methods, Elsevier Ltd: 87-109.
    22.
  22. Jones AP, Wall F, Williams CT (1996) Rare earth minerals-chemistry, origin and ore deposits; Chapman & Hall: London, UK.
    23.
  23. Jorjani E, Bagherieh AH, Chelgani SC (2011) Rare earth elements leaching from Chadormalu apatite concentrate: Laboratory studies and regression predictions. Korean Journal of Chemical Engineering. 28: 557–562.
    24.
  24. Kanen R (2001) Distinguishing between S and I type granites. Minerals Services, Melbourne, Australia.
    25.
  25. Kim E, .Osseo-Asare K (2012) “Aqueous stability of thorium and rare earth metals in monazite hydrometallurgy: Eh–pH diagrams for the systems Th–, Ce–, La–, Nd– (PO4)–(SO4)–H2O at 25 C” Hydrometallurgy  113–114: 67-78.
    26.
  26. Kim E, Bae I, Chai S, Shin H (2009) Mechano-chemical decomposition of monazite to assist the extraction of rare earth elements, Journal of Alloys and compounds 3;486(1-2):610-4.
    27.
  27. Kim E, Osseo-Asare K (2012) Aqueous stability of thorium and rare earth metals in monazite hydrometallurgy: Eh–pH diagrams for the systems Th–, Ce–, La–, Nd– (PO4)–(SO4)–H2O at 25 C, Hydrometallurgy 113–114: 67-78.
    28.
  28. Kim R, Cho H, Han KN, Kim K, Mun M (2016) Optimization of acid leaching of rare earth elements from Mongolian Apatite-Based Ore Minerals     30;6(3):63.
    29.
  29. Kumari A, Panda R, Jha MK, Lee JY, Kumar JR, Kumar V (2014) Thermal treatment for the separation of phosphate and recovery of rare earth metals (REMs) from Korean monazite, Journal of Industrial and Engineering Chemistry 21: 696-703.
    30.
  30. Middlemost EAK (1994) Magmas and magmatic rocks, an introduction to igneous petrology, Longman, London.
    31.
  31. Mokhtari MAA, Sadeghi M, NabatianGh (2018) Geochemistry and potential resource of rare earth element in the IOA deposits of Tarom area, NW Iran. Journal of Ore Geology Reviews 92:529–541.
    32.
  32. NabatianGh, Ghaderi M (2013) Oxygen isotope and fluid inclusion study of the Sorkhe- Dizaj iron oxide-apatite deposit, NW Iran. International Geology Review 55(4): 397-410.
    33.
  33. NabatianGh, Ghaderi M (2014) Mineralogy and geochemistry of rare earth elements in iron oxide-apatite deposits of the Zanjan region. Scientific Quarterly Journal of Geosciences, Geological Survey and Mineral Exploration of Iran 24:157–170.
    34.
  34. NabatianGh, Li XH, Honarmand M, Melgarejo JC (2017) Geology, mineralogy and evolution of iron skarn deposits in the Zanjan district, NW Iran: Constraints from U-Pb dating, Hf and O isotope analyses of zircons and stable isotope geochemistry. Ore Geology Reviews 84:42–66.
    35.
  35. Pearce JA (1996) Sources and setting of granitic rocks. Episodes 19(4):120-5.
    36.
  36. Pearce JA, Harris NBW, Tindle AG (1984) Trace element discrimination diagrams for the tectonic interpretation of granitic rocks. Journal of Petrology 25: 956 – 983.
    37.
  37. Pereira F, Bilal E (2016) Phosphoric acid extraction and rare earth recovery from apatites of the Brazilian phosphates ores. Romanian journal of Mineral Deposits 85(2):49-52.
    38.
  38. Preston JS, Cole PM, Craig WM, Feather AM (1996) the recovery of rare earth oxides from a phosphoric acid by product. Part 1: Leaching of rare earth values and recovery of a mixed rare earth oxide by solvent extraction Hydrometallurgy 41(1):1-9.
    39.
  39. Sandström A, Fredriksson A (2012) Apatite for extraction leaching of Kiirunavaaraapatite for simultaneous production of fertilizers and REE. In Proceedings of the 26th International Mineral Processing Congress, IMPC 2012: Innovative Processing for Sustainable Growth, New Delhi, India, 24–28: 4707–4714.
    40.
  40. Sarem MN, Abedini MV, Dabiri R, Ansari MR. (2021) Geochemistry and petrogenesis of basic Paleogene volcanic rocks in Alamut region, Alborz mountain, north of Iran. Earth Sciences Research Journal 25(2): 237-245.
    41.
  41. Şengör AMC, Nataln'in BA (1996) Paleotectonics of Asia: Fragments of a synthesis, In: Yin AM, Harrison T (eds.), The Tectonic Evolution of Asia. Cambridge University Press: 486-640.
    42.
  42. Stockli DF, Hassanzadeh J, Stockli LD, Axen G, Walker JD, Dewane TJ (2004) Structural and geochronological evidence for Oligo-Miocene intra-arc low angle detachment faulting in the Takab-Zanjan area, NW Iran. Abstract, Programs Geological Society of America 36: 319.
    43.
  43. Sun SS, Mc Donough WF (1989) Chemical and isotopic systematics of ocean basalts: implications for mantle composition and processes. In: Saunders A D, and Norry, M J. (Eds.), Magmatism in the ocean basins. Geological Society of London, Special Publication, 42. Black Well, Oxford,:313 – 346.
    44.
  44. Thirlwall, M. F., Smith, T. E., Graham, A. M., Theodorou, N., Hollings, P., Davidson, J. P. and Arculus, R. J. (1994) High field strength elements anomalies in arc lava: source or process? Journal of petrology 1;35(3):819-38.
    45.
  45. Villaseca C, Barbero L, Herreros V (1998) A re-examination of the typology of peraluminous granite types in intracontinental orogenic belts. Earth and Environmental Science Transactions of the Royal Society of Edinburgh 89: 113–119
    46.
  46. Wang L, Long Z, Huang X, Yu Y, Cui  D, Zhang G (2010) Recovery of rare earths from wet-process phosphoric acid. Hydrometallurgy 101: 41–47.
    47.
  47. Yazdi A, Shahhosseini E, Moharami F (2022) Petrology and tectono-magmatic environment of the volcanic rocks of West Torud–Iran, Iranian Journal of Earth Sciences 14 (1): 40-57.
    48.
  48. Yazdi A, Ziaaldini S, Dabiri R (2015) Investigation on the Geochemical Distribution of REE and Heavy Metals in Western Part of Jalal-Abad Iron Ore Deposit, Zarand, SE of Iran, Open journal of ecology 5 (09): 460-476.
    49.

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