Investigation on Photocatalytic Activity of Perovskite ZnTiO3 and CdTiO3 Nanocrystals for Degradation of Crystal Violet and Congo Red Pollutants under Sunlight
Subject Areas : International Journal of Bio-Inorganic Hybrid Nanomaterials
Keywords: Photocatalytic, Azo Dyes, CdTiO3, Perovskite nanocrystal, ZnTiO3,
Abstract :
Perovskite nanocrystals of ZnTiO3 and CdTiO3 with the cubic and orthorhombic structureswere synthesized using the hydrothermal method. The crystal structures confirmed by XRD, morphologyand particle size, chemical composition, and surface chemical features of samples synthesized areevaluated through, Fe-SEM, TEM, EDX , FT-IR, and BET analyzes. The average crystallites sizeZnTiO3 and CdTiO3 perovskite were determined 12.03 and 43.7 nm, respectively by Debye Scherer’srelationship.The Optical and photocatalytic properties of ZnTiO3 and CdTiO3 are investigated byDRS (Differential reflectance spectroscopy) and UV-Vis analysis, respectively. The Ebg value (bandgap energy) of the perovskites was obtained using Tauc plots. The cubic ZnTiO3 showed Ebg=3.11 eVagainst the CdTiO3 with Ebg=3.39 eV. The photocatalytic activities of perovskite ZnTiO3 and CdTiO3nanocrystals were evaluated for degradation Congo red (CR) and Crystal violet (CV) pollutants. TheZnTiO3 degraded both the CR and CV dyes with high efficiency (91% and 72%) compared with CdTiO3perovskite (51% and 9.7%) under 60 min of the sunlight irradiation. This high performance is affectedby factors such as narrowing of the Ebg, the larger surface area, smaller crystal size and the existence ofthe hierarchical porous in the structure of the ZnTiO3 than CdTiO3. The kinetics studies revealed the rateconstant of photodegradation of CR anionic dye by both of the perovskite as-synthesized is greater thandegradation of cationic CV. The decomposition of the crystal violet fits the pseudo-first-order kinetic,while the degradation of the CR follows both the pseudo-first-order and the pseudo-second-order kineticaccording to R2> 0.9.