A One-Pot Synthesis of Highly Functionalized Ketenimines by a Three-component 2-Thioxothiazolidin-4-one, Alkyl Isocyanides and Dialkyl Acetylenedicarboxylates

محورهای موضوعی : پلیمر

Khadijeh Yadollahzadeh ¹

1 -

تاریخ دریافت : 1394/10/07 تاریخ پذیرش : 1394/10/07 تاریخ انتشار : 1394/10/11

کلید واژه:

چکیده مقاله :

The 1:1 reactive intermediates produced in the reaction between alkyl isocyanides and dialkyl acetylenedicarboxylates were trapped with 2-thioxothiazolidin-4-one to generate to highly functionalized ketenimines. A series of new 2-thioxothiazolidin-4-one derivatives were synthesized in moderate yields. The advantages of the present method include good functional group tolerance and simple experimental procedure and purification