بررسی اثر روش لایه نشانی دی‌اکسید تیتانیوم (TiO2) بر عملکرد سلول خورشیدی حساس شده با رنگدانه‌ (DSSC)

محورهای موضوعی : عملیات حرارتی

فرشته مومنی ¹ , مهرداد کاشفی تربتی ²

1 - کارشناس ارشد، مهندسی مواد، دانشگاه فردوسی، مشهد
2 - دانشیار، گروه مهندسی مواد و متالورژی، دانشگاه فردوسی، مشهد

تاریخ دریافت : 1394/06/24 تاریخ پذیرش : 1394/06/24 تاریخ انتشار : 1394/06/01

کلید واژه: سلول خورشیدی حساس شده با رنگدانه‌, روش دکتر بلید, روش پوشش‌دهی چرخشی,

چکیده مقاله :

جزء اصلی در یک سلول خورشیدی حساس شده با رنگدانه (DSSC) فتوالکترود است که شامل زیرلایه‌ی پوشیده شده با یک اکسید نیمه رسانا می‌باشد. در این تحقیق اثر دو روش لایه نشانی دکتر بلید و پوشش‌دهی چرخشی بر عملکرد و بازده DSSC مورد بررسی قرار گرفتند. نتایج نشان می‌دهد که در روش پوشش‌دهی چرخشی، تخلخل و جذب رنگدانه کمتر از روش دکتر بلید است، اما به علت ایجاد یک پوشش کم ترک و پیوسته بازده DSSC بیشتر از روش دکتر بلید است.

منابع و مأخذ:

[1]     D. I. Klaus Petritsch, “Organic Solar Cell Architectures”, Ph. D. Thesis University of Cambridge, United Kingdom, 2000.

 [2]     Z. Yu, “Liquid Redox Electrolytes for Dye-Sensitized Solar Cells”, Ph.D. Thesis, KTH Chemical Science and Engineering, Royal Institute of Technology Stockholm, 2012.

 [3]     J. Minutillo, B. Lundgren, J. Lane & J. Widera, “Development of TiO₂ Nanoparticle-Based Solar Cells”, Adelphi University, Garden City, 2007.

 [4]     M. SOKOLSKÝ&  J. CIRÁK, “Dye-Sensitized Solar Cells: Materials and Processes”, Acta Electrotechnica et Informatica, Vol. 10, No. 3, pp. 78–81, 2010.

 [5]     S. Wenger, “Strategies to Optimizing Dye-Sensitized Solar Cells: Organic Sensitizers, Tandem Device Structures and Numerical Device Modeling”, Ph. D. Thesis University of Swiss Federal Institute of Technology in Lausanne, Suisse, 2010.

 [6]     S. Ito, T. Murakami, P. Comte, P. Liska, C. Grätzel, M. Nazeeruddin&  M. Grätzel, “Fabrication of thin film dye sensitized solar cells with solar to electric power conversion efficiency over 10%”, Thin Solid Films, Vol. 516, pp. 4613–4619, 2007.

 [7]     B. O’Regan & M. Grätzel, “A low-cost, highefficiency solar cell based on dye-sensitized colloidal TiO2 films”, Nature, Vol. 353, pp. 737–740, 1991.

 [8]     Y. Chiba, A. Islam, Y. Watanabe, R. Komiya, N.Koide & L. Han, “Dye-Sensitized Solar Cells with Conversion Efficiency of 11.1%”, Japanese Journal of Applied Physics, Vol. 45, No. 25, pp. L638–L640, 2006.

 [9]     M. R. Mohammadi, R. R. M. Louca, D. J. Fray & M. E. Welland, “Dye-sensitized solar cells based on a single layer deposition of  TiO₂ from a new formulation paste and their photovoltaic performance”, Solar Energy, Vol. 86, pp. 2654–2664, 2012.

 [10] M. Grätzel & A. J. McEvoy, “Principles and Applications of Dye Sensitized Nanocrystalline Solar Cells (DSC)”, Laboratory for Photonics and Interfaces, ICMB-FSB, Ecole Polytechnique Fédérale de Lausanne, CH-1015 Lausanne, Switzerland, Asian J. Energy Environ., Vol. 5, Issue 3, pp. 197-210, 2004.

 [11] M. Grätzel, “Photovoltaic performance and long-term stability of dye-sensitized meosocopic solar cells”, C. R. Chimie, Vol. 9, pp. 578–583, 2006.

 [12] L. Moreira Gon, V. Bermudez, H. A. Ribeiroa & A. M. Mendes, “Dye-sensitized solar cells: A safe bet for the future”, Energy Environ. Sci, Vol. 1, pp. 655–667, 2008.

 [13] Zh. Wei, “Fabrication of Dye-Sensitized Solar Cells with Enhanced Energy Conversion Efficiency”, Ph.D. Thesis, National university of Singapore, 2011.

 [14] K. J. Hwang, S. J. Yoo, S. H. Jung, D. W. Park, S. Kim & J. W. Lee, “Synthesis and Characterization of Nanostructured Titania Films for Dye-Sensitized Solar Cells”, Bull. Korean Chem. Soc, Vol. 30, No. 1, pp. 172-176, 2009.

 [15] G. J. Yang, C. J. Li, S. Q. Fan & J. C. Gao, “Influence of pore structure on ion diffusion property in porous TiO₂ Coating and photovoltaic performance of dye-sensitized solar cells”, Surface & Coatings Technology, Vol. 205, pp. 3205–3210, 2011.

 [16] H. Chang, H. T. Su, W. A. Chen, K. D. Huang, S. H. Chien, S. L. Chen & C. C. Chen, “Fabrication of multilayer TiO₂ thin films for dye-sensitized solar cells with high conversion efficiency by electrophoresis deposition”, Solar Energy, Vol. 84, pp. 130–136, 2010.

 [17] C. S. Chou, F. C. Chou, Y. G. Ding & P. Wu, “The effect of ZnO-coating on the performance of a dye-sensitized solar cell”, Solar Energy, Vol. 86, pp. 1435–1442, 2012.

 [18] C. Lun Yu, “Titanium Dioxide Thick Film Printing Paste For Dye Sensitized Solar Cell”, Case Western Reserve University, 2011.

 [19] S. Agarwala, “Nano structured Metal-Oxide Materials for Dye-Sensitized Solar Cells”, Ph.D. Thesis, National university of Singapore, 2011.

 [20]  A. El. Tayya, “Dye-sensitized solar cell: parameters calculation and model integration”, Journal of Electron Devices, Vol. 11, pp. 616-624, 2011.

 [21] A. Tolvanen, “Characterization and Manufacturing Techniques of Dye-Sensitized Solar Cells”, Master’s Thesis, Helsinki University of Technology, 2003.

 [22] J. Wan, Y. Lei, Y. Zhang, Y. Leng & J. Liu , “Study on TiO₂ photoelectrode to improve the overall performance of dye-sensitized solar cells”, Electrochimica Acta, Vol. 59, pp. 75- 80, 2012.

 [23] S. Ito, T. N. Murakami, P. Comte, P. Liska, C. Grätzel, M. K. Nazeeruddin & M. Grätzel, “Fabrication of thin film dye sensitized solar cells with solar to electric power conversion efficiency over 10%”, Thin Solid Films, Vol. 516, pp. 4613-4619, 2008.

 [24] Ch. Noumissing Sao, “Dye-Sensitized Solar Cells Based on Perylene Derivatives”, Ph.D. Thesis, Kassel University, 2009.