بررسی تاثیر پارامترهای ژئومورفیک و هیدرولوژیک در آلودگی آب ارتفاعات جغتای (با تاکید برآرسنیک)
محورهای موضوعی :
آب و محیط زیست
موسی الرضا لطفیان
1
(کارشناس ارشد جغرافیای طبیعی (ژئومورفولوژی)، گروه اقلیم و ژئومورفولوژی، دانشکده جغرافیا و علوم محیطی، دانشگاه حکیم سبزواری، شهر سبزوار، کشور ایران. *(مسوول مکاتبات))
ابوالقاسم امیر احمدی
2
(دانشیار ژئومورفولوژی، گروه اقلیم و ژئومورفولوژی، دانشکده جغرافیا و علوم محیطی، دانشگاه حکیم سبزواری، شهر سبزوار، کشور ایران.)
علی اکبر شایان یگانه
3
(دکترای ژئومورفولوژی، گروه آموزش ابتدایی، مرکز علامه طباطبایی، دانشگاه فرهنگیان، شهر سبزوار، کشور ایران.)
تاریخ دریافت : 1401/12/16
تاریخ پذیرش : 1402/02/04
تاریخ انتشار : 1402/06/01
کلید واژه:
آرسنیک,
SPSS,
کیفیت آب,
غلظت,
چکیده مقاله :
زمینه و هدف: آلودگی آب ها به عنصر سمی آرسنیک دارای دو منشأ زمین زاد و بشر زاد می باشد. وجود لایه ها و واحدهای زمین شناسی غنی از آرسنیک محلول در آب می تواند سبب آلودگی آب های زیر زمینی و سطحی شود. بالا بودن غلظت آرسنیک از حد مجاز آن در آب 10 میلی گرم در لیتر، می تواند موجب اختلالاتی در سلامتی انسان ها و همچنین بروز سرطان شود.
روش بررسی: در این تحقیق از منابع آب سطحی و زیرزمینی در 10 ایستگاه واقع در دو یال شمالی و جنوبی ارتفاعات جغتای در اردیبهشت ماه 1393 نمونه برداری آن جام شد. سپس نمونه ها برای آنالیز به آزمایشگاه آنالیز شیمی دانشگاه فردوسی مشهد ارسال شد و با استفاده از روش طیف سنج جذب اتمی آنالیز های مورد نظر انجام گرفت.
یافته ها: معلوم شد اولاّ لیتولوژی منطقه درکیفیت آب توآن استه تاثیر بگذارد، به طوری که غلظت آرسنیک در نمونه ها بین 9/1 تا 7/6 میلی گرم درلیتر متغیر است؛ ثانیاّ جهت شیب لایه زمین شناسی بر میزان آلودگی آب به آرسنیک تاثیر داشته است و بر این اساس بیش ترین غلظت آرسنیک در دامنه شمالی و در جهت شیب لایه زمین شناسی ثبت شده است؛ ثالثاّ میزان آرسنیک محلول در آب با pH آب رابطه مستقیمی ندارد.
بحث و نتیجه گیری: بر این اساس می توان نتیجه گرفت که غلظت آرسنیک در نمونه های انتخابی در حد مجاز می باشد و لیکن نوساناتی در میزان آرسنیک محلول در آب مشاهده می شود.
چکیده انگلیسی:
Background and Objective: Water contamination with the toxic arsenic element comes from two sources of human and Earth. The layers and water-soluble arsenic-rich geological units can contaminate both ground and surface water sources. The high concentration of arsenic in water limit of 10 milligrams per liter higher than its standard amount can cause disruptions in human health as well as creating cancer.
Material and Methodology: In this study, samples of surface and ground water resources at 10 stations in northern and southern Vial located in highlands of Joghtay were gathered in April 2014. Then the samples were sent to Laboratory of Mashhad Ferdowsi University to analyze chemically. The analysis was planned to be done by atomic absorption spectrometry method.
Findings: This shows that: (1) The litology of the region has affected the water quality, so that the arsenic density varies from 1.9 to 6.7 m/l. (2) The direction of the slope of Geology layers has affected on the arsenic contamination of water and based of this consumption the highest concentrations of arsenic is in the northern slopes and in the direction of slope Geology layers which has been recorded. (3) Arsenic dissolved in water has no direct correlation with pH.
Discussion and Conclusion: It concluded that the arsenic density in the selected samples were at the standard level. But some fluctuations were seen in the water-soluble arsenic.
منابع و مأخذ:
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US EPA. 2002. Methods for measuring the acute toxicity of effluents and receiving waters to freshwater and marine organisms,5th Ed.US Environmental Protection Agency Office of Water, Washington DC.
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Akbulut, M., Piskin, O. & Karayigit, A., 2006- The genesis of the carbonatized and silicified ultramafics known as listvenites: a case study from the Mihaliccik region (Eskisehir) NW Turkey. Geological Journal, 41, 557-580
Geen, V., 2003. "Spatial variability of arsenic in 6000 tube wells in a 25 km2 area in Bangladesh ", Water Resources Research, 39, 1140
Liu, F., A. De Cristofaro and A. Violante. 2001. Effect of pH, phosphate and oxalate on the adsorption/desorption of arsenate on/from goethite. Soil Science 166: 197-208.
Hakan, A., Turan, N. A. 2015. Estimation of spatial distribution of heavy metals in groundwater using interpolation methods and multivariate statistical techniques; its suitability for drinking and irrigation, Environmental Monitoring and Assessment, 187: 1-13.
Hudson-Edwards K. A., Jamieson H. E., Charnock J. M., Macklin M.G. 2005. Arsenic speciation in waters and sediments of ephemeral floodplain pools, ríos Agrio-Guadiamar, Aznalcóllar, Spain Chem Geol, 219(1-4):175-192.
Corwin, D. L., A. David and S. Goldberg. 1999. Mobility of arsenic in soil from the Rocky Mountain Arsenal area. Contaminant Hydrology 39: 35-58.
S. geological Survey. 2001.As in grand water of Willamette basin, Oregon.
Anawar, H. M Akai, J, Komaki, K, Terao, H, Yoshioka, T, Ishizuka, T, Safiullah, S, Kato, K, 2003, Geochemical occurrence of arsenic in groundwater of Bangladesh: sources and mobilization processes, Journal of Geochemical Exploration 77, 109–131.
Marcus S., 2007. Mobilisation of geogenic arsenic into groundwater in Västerbotten County, Sweden, thesis of Uppsala University.
Alsubih, M, El Morabet, R, Abad Khan, R, Ahmad Khan, N, Haq Khan, M, Ahmed, S, Abdul Qadir & Changani , F , 2021. Occurrence and health risk assessment of arsenic and heavy metals in groundwater of three industrial areas in Delhi, India , Environmental Science and Pollution Research volume 28, pages63017–63031.
Dhamija, S, Joshi, H, 2022. Prediction of Groundwater Arsenic Hazard Employing Geostatistical Modelling for the Ganga Basin, India, Water, 14, 2440. https://doi.org/10.3390/w14152440
Shahdadi, S, Muslempour M. A, 2011. Studying the contamination of southeast Tehran sediments with toxic elements using principal component analysis method and determination of pollution index, Journal of Environmental Science, year 37, number 60, pp137-148. (In Persian)
Fathi Hafeshjani, Z, Lotfi, M, Alireza S, 2018, Investigation of Arsenic Contamination in the Soils of the Western Area of Bijar, Proceedings of the 30th Earth Sciences Meeting, March 1st to 3rd, 2018, pp. 1-8. (In Persian)
Nowrozi, H; Nadiri, A; Asghari Moghadam, 2015. A. Investigation of arsenic contamination of Malkan Plain underground water, Ecohydrology, Volume 3, Number 2, pp. 166-151. (In Persian)
Behbahani Nia, A. Farahani, M., 2016. Investigating the source of arsenic contamination of natural resources in Hashtroud city, East Azarbaijan province, Environmental Science and Technology, Volume 18, Special Issue No. 2, 475-469. (In Persian)
Tozandeh Jani, M.; Safianian, A. r Mirghafari, N.A.; Soleimani, M., 2016. assessment of the probability of arsenic contamination in the underground water of Hamedan-Bahar plain using geostatistical methods, Water and Soil Journal (Agricultural Sciences and Industries), Volume 31, Number 3, pp. 885-874. (In Persian)
Haq Parast, M.; Tarshizian, H. A; Dabiri, R., Assessment of the concentration of heavy metals and the level of pollution in sediments, Alme Jouk ophiolitic region (northeast of Iran), Environmental Science and Technology, 2018. Volume 21, Number 4, 91-105. (In Persian)
Beikpour, Sh. Arghvan, Z, 2019. Anomaly investigation and its possible origins in the underground water of Maragheh study area, Environmental Sciences and Technology, Volume 22, Number 3, 264-254. (In Persian)
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Mandal, B.K., Suzuki, K., 2002. Arsenic round the world: a review, Talanta, 58, 201-235.
Baig, J.A, Kazi, T. G, Shah, A.O, Kandhro, G.K, Afridi,H.I Arain M.B , Jamali M.K , Nusrat Jalbani, N, 2010. Speciation and evaluation of Arsenic in surface water and groundwater samples: A multivariate case study, Ecotoxicology and Environmental Safety 73 (2010) 914–923
Rahnama S, Khaledian M. R., Shahnazari A., Forghani A. A. 2011. geostatistically based evaluation of heavy metals concentration in groundwater resources of Central Guilan. Proceedings of the 4th Iran Water Resources Management Conference 2011; 12. (In Persian)
Nriagu, J.O. (1989). A global assessment of natural sources of atmospheric trace metals. Nature, Vol.338, pp.47–49.
US EPA. 2002. Methods for measuring the acute toxicity of effluents and receiving waters to freshwater and marine organisms,5th Ed.US Environmental Protection Agency Office of Water, Washington DC.
Coleman, R.G., 1997. Ophiolites: Ancient oceanic lithosphere. springer–verlag Berlin, 229 p
Akbulut, M., Piskin, O. & Karayigit, A., 2006- The genesis of the carbonatized and silicified ultramafics known as listvenites: a case study from the Mihaliccik region (Eskisehir) NW Turkey. Geological Journal, 41, 557-580
Geen, V., 2003. "Spatial variability of arsenic in 6000 tube wells in a 25 km2 area in Bangladesh ", Water Resources Research, 39, 1140
Liu, F., A. De Cristofaro and A. Violante. 2001. Effect of pH, phosphate and oxalate on the adsorption/desorption of arsenate on/from goethite. Soil Science 166: 197-208.
Hakan, A., Turan, N. A. 2015. Estimation of spatial distribution of heavy metals in groundwater using interpolation methods and multivariate statistical techniques; its suitability for drinking and irrigation, Environmental Monitoring and Assessment, 187: 1-13.
Hudson-Edwards K. A., Jamieson H. E., Charnock J. M., Macklin M.G. 2005. Arsenic speciation in waters and sediments of ephemeral floodplain pools, ríos Agrio-Guadiamar, Aznalcóllar, Spain Chem Geol, 219(1-4):175-192.
Corwin, D. L., A. David and S. Goldberg. 1999. Mobility of arsenic in soil from the Rocky Mountain Arsenal area. Contaminant Hydrology 39: 35-58.
S. geological Survey. 2001.As in grand water of Willamette basin, Oregon.
Anawar, H. M Akai, J, Komaki, K, Terao, H, Yoshioka, T, Ishizuka, T, Safiullah, S, Kato, K, 2003, Geochemical occurrence of arsenic in groundwater of Bangladesh: sources and mobilization processes, Journal of Geochemical Exploration 77, 109–131.
Marcus S., 2007. Mobilisation of geogenic arsenic into groundwater in Västerbotten County, Sweden, thesis of Uppsala University.
Alsubih, M, El Morabet, R, Abad Khan, R, Ahmad Khan, N, Haq Khan, M, Ahmed, S, Abdul Qadir & Changani , F , 2021. Occurrence and health risk assessment of arsenic and heavy metals in groundwater of three industrial areas in Delhi, India , Environmental Science and Pollution Research volume 28, pages63017–63031.
Dhamija, S, Joshi, H, 2022. Prediction of Groundwater Arsenic Hazard Employing Geostatistical Modelling for the Ganga Basin, India, Water, 14, 2440. https://doi.org/10.3390/w14152440
Shahdadi, S, Muslempour M. A, 2011. Studying the contamination of southeast Tehran sediments with toxic elements using principal component analysis method and determination of pollution index, Journal of Environmental Science, year 37, number 60, pp137-148. (In Persian)
Fathi Hafeshjani, Z, Lotfi, M, Alireza S, 2018, Investigation of Arsenic Contamination in the Soils of the Western Area of Bijar, Proceedings of the 30th Earth Sciences Meeting, March 1st to 3rd, 2018, pp. 1-8. (In Persian)
Nowrozi, H; Nadiri, A; Asghari Moghadam, 2015. A. Investigation of arsenic contamination of Malkan Plain underground water, Ecohydrology, Volume 3, Number 2, pp. 166-151. (In Persian)
Behbahani Nia, A. Farahani, M., 2016. Investigating the source of arsenic contamination of natural resources in Hashtroud city, East Azarbaijan province, Environmental Science and Technology, Volume 18, Special Issue No. 2, 475-469. (In Persian)
Tozandeh Jani, M.; Safianian, A. r Mirghafari, N.A.; Soleimani, M., 2016. assessment of the probability of arsenic contamination in the underground water of Hamedan-Bahar plain using geostatistical methods, Water and Soil Journal (Agricultural Sciences and Industries), Volume 31, Number 3, pp. 885-874. (In Persian)
Haq Parast, M.; Tarshizian, H. A; Dabiri, R., Assessment of the concentration of heavy metals and the level of pollution in sediments, Alme Jouk ophiolitic region (northeast of Iran), Environmental Science and Technology, 2018. Volume 21, Number 4, 91-105. (In Persian)
Beikpour, Sh. Arghvan, Z, 2019. Anomaly investigation and its possible origins in the underground water of Maragheh study area, Environmental Sciences and Technology, Volume 22, Number 3, 264-254. (In Persian)
