استفاده از نانوگاما آلومینا به عنوان جاذب به منظور حذف نیکل و کبالت از پساب صنایع معدنی
محورهای موضوعی : آلودگی محیط زیست (آب و فاضلاب)
فریبا سلیمانی
1
(کارشناسی ارشد آلودگی های محیط زیست واحد علوم و تحقیقات تهران، دانشگاه آزاد اسلامی،تهران، ایران)
محمد هادی گیویان راد
2
(استادیار گروه شیمی واحد علوم و تحقیقات تهران،دانشگاه آزاد اسلامی، تهران، ایران(مسئول مکاتبات))
امیرحسین حقیقتی
3
(دکترای شیمی کاربردی، گروه شیمی، واحد تهران شمال دانشگاه آزاد اسلامی، تهران، ایران)
کلید واژه: نیکل و کبالت, پساب های صنعتی, حذف, گاما نانوآلومینا,
چکیده مقاله :
زمینه و هدف: توسعه شهرنشینی و صنایع، منجر به افزایش میزان فاضلاب و پساب تولیدی گردیده است. دفع ناقص و غیر اصولی این فاضلاب ها باعث ورود مقادیر زیادی فلزات سنگین به محیط زیست شده که حذف آن ها از آب و پساب به عنوان آلودگی هایی که از نظر زیستی تجزیه ناپذیرند، برای حفظ محیط زیست و سلامت عمومی بسیار مهم است. روش بررسی: در این مطالعه به سنتز و بررسی ساختاری گاما نانو آلومینا سنتز شده به عنوان یک جاذب با کارایی بالا در حذف فلزات سنگین نیکل و کبالت پرداخته شده و با استفاده از طراحی آزمایش با نرم افزار DX7 اثر شرایط متفاوتی از قبیل میزان غلظت اولیه فلزات سنگین، مقدار نانو جاذب و pH بررسی گردید. یافته ها: نتایج آنالیز XRD، FTIR، SEM و EDX ساختار گاما نانو آلومینا را تائید نموده و مقدار فلزات محتوی با روش اسپکتروفتومتری UV-Vis اندازه گیری شده است. نانو گاما آلومینا بعنوان یک جاذب قدرتمند قادر به جذب بالای نیکل و کبالت در محیط های آبی با pH قلیایی بوده به طوریکه در نمونه های آزمون، 66/98% نیکل و 1/95% کبالت و در نمونه های حقیقی نیز 100% آن ها حذف گردیده است. بحث ونتیجه گیری: با بررسی نتایج مشخص گردید که گاما نانو آلومینا سنتز شده می تواند به عنوان یک نانو جاذب مقرون به صرفه و کارا جهت حذف فلزات سنگین محسوب شود که این امر توسط ایزوترم های جذب فرندلیچ و لانگمویر مورد بررسی و تایید قرار گرفت و مشخص گردید که فرایند جذب (تک لایه ای یا چند لایه ای، یکنواختی یا ناهمگن بودن) این عناصر توسط جاذب نانوگاما آلومینا ، از معادله جذب فرندلیچ و لانگمویر پیروی می کنند.
Background and Objective: The development of urbanization and industries has led to an increase in sewage and wastewater production. The defective and non-standard disposal of these wastewaters has resulted in influx of large amounts of heavy metals into the environment which their removal, as bio-irresolvable contaminants, from water and wastewater are considerably important for protecting environment and public health. Method: In this study, gamma Nano-alumina was synthesized and its structural analysis was characterized, which was applied as a high performance adsorbent for heavy metals Nickel and Cobalt. Moreover, by using DX7 software for experiment design, the effects of different conditions such as heavy metals initial concentration, Nano-adsorbent amount and pH were modified. Findings: The results of XRD, FTIR, SEM and EDX analysis, confirmed the existence of gamma Nano-alumina structure, and Nickel and Cobalt contents were determined by UV-Vis spectrophotometry method. Nano gamma alumina, as a powerful adsorbent, could be adsorbed the high levels of Nickel and Cobalt in alkaline pH-rich environments, then in experimental samples, 98.66% of Nickel and 95.1% of Cobalt and in real samples, 100% was eliminated. Discussion and Conclusion: It was found that synthesized gamma Nano-alumina could be considered as a cost-effective and high-performance Nano-absorbent for heavy metals elimination. Consequently, it was verified by Freundlich and Langmuir adsorption isotherms, which the adsorption process of these elements with the Nano-alumina absorbent followed by Freundlich and Langmuir adsorption equation.
1. Sadeghi, Sayed Shams al-Din, Naderi Masoud, An Analysis of the Dimensions of Gavernment Security in Iran of the Twenty-First Century, State Research Spring 1395, Volume 2, Issue 5, pp 165-202. (In Persion)
2. Sadeghi, Seyed Kamal et al ; Estimation of Economic Footprint in Economic Sectors in Iran by Social Accounting Matrix Approch . Quantitative Economics, Winter ,1395, Volume 11, Issue 3, pages 81-111, (In Persion)
3. Sallaryan, Mohammad,Development of Water Resources and New Management Developments in Irrigation, Water and Sustinable Development, 1393, Volume 1, Issue 2. (In Persion)
4. Mortazavi, Seyed Mostafa et al., Water Resources Management and Sustinable Development. Case Study ;Rafsnjan Plain Water and West Water ,2011, Volume 22, Issue2, pages 126-131. (In Persion)
5. Marandi, Reza Ebrahim Zarandi, Mohammad Javad, Investigation of Biological Treatment of Acid Drinage Water of Sarcheshmeh Copper Mine Based on the Function of Reactors with Conscuative Operations (SBR) ,Journal of Enviromental Science and Technology, Autuman 2010, Volume 12, Issue 3, Pages 35-44. (In Persion)
6. Yavari, Mohsen et al., Removal ., of Heavy Metals from Wastewater from Solid Waste Indusries in Zanjan , 16th National Conference on Enviromental Helth in Iran, 1392, Oct.9-11 Tabriz, Iran. (In Persion)
7. Dehghani, Mansoure et al., Investigating the Concentration of Heavy Metals in Drinking Water Resources of Shiraz,16 th National Conference on Enviromental Health of Iran,. 1392, Octobrer 9-11, Tabriz, Iran. (In Persion)
8. Alizadh, Reza Abedini , Soda. Applications of Nanotechnology in Enviromental Engineering. Human and Enviromental, Summer 2010, Volume 8, Issue 2, Pages 3-11. (In Persion)
9. Karimi Takanlou, Leila et al., Evaluation of the Absorption Process of Cadmium Ions from Synthetic Sewage with synthesized magnetic nanoparticles , Journal of healthes and Enviroment, Oct 2014, Volume 7, Issue 2, Pages 84-171. (In Persion)
10. Hossein Shahi Bandri, Coral, Application of Nanotechnology in Surface Water Under ground, and Westwater Treatment , Human and Enviroment,Summer, 2012 , Volum 10, Issue 2, Pages 27-32. (In Persion)
11. Darban, A.K., Kianinia Y., Taheri-Nassaj, E., 2013, Synthesis of nano-alumina powder from impure kaolin and its application for arsenite removal from aqueous solutions, Journal of Environmental Health Science and Engineering, Vol. 11(1), pp. 1-11.
12. Srivastava, V., Weng C.H., Singh V.K., Sharma Y.C., 2011, Adsorption of nickel ions from aqueous solutions by nano alumina: kinetic, mass transfer, and equilibrium studies, Journal of Chemical & Engineering Data, Vol. 56(4), pp. 1414-1422.
13. Saber, O., 2012, Novel self assembly behavior for γ-alumina nanoparticles, Particuology, Vol.10(6), pp.744-750.
14. Hoseinian, F.S., Irannajad M., Javadi Nooshabadi, A., 2015, Ion flotation for removal of Ni (II) and Zn (II) ions from wastewaters, International Journal of Mineral Processing, Vol.143, pp. 131-137.
15. Saeedi Far, M., Vahabzadeh Roodsari, H., Zamini, A., Mirrasooli, E., Kazemi, R., 2012, The effects of diazinon on behavior and some hematological parameters of fry rainbow trout(Oncorhynchus mykiss), World Journal of Fish Marine Science, Vol. 4, pp. 369-375.
16. Oohadi, Vahid Reza,Amiri, Mohammad Enviromental Geothechnics of Nano Clays in Intraction With Heavy Metal Pollutions ,Civil Engineer, Winter 2010, Volume 42, Issue 3, Pages 29-36. (In Persion)
17. Talei Bejarbone , Fetane et al., Removal of Heavi Metal(Copper) using Spirulina Platensis by Taguchi Methode, Aquatic Ecology Journal, Autumn 2013, Volume 5, Issue 2, Pages 124-134 . (In Persion)
18. Vali Nezahad, Fatemh et al., Study of Heavi Metals (Cadmium. Crumium, Nikel, Lead, Zink) In Slamshahr Under Ground Water Resources and its distibitution Map in GIS Enviroment Journal of Enviromental Science and Technology, Autumn 1395, Volume 18, No 2, Pages 187-199. (In Persion)
19. Mallakootian, M., Almasi, A ., Hosseini, H., 2018, Pb and Co removal from paint industries effluent using wood ash, International Journal of Enviromental Science & Technology , Vol 5(2), pp 217-222.
20. Hamzh, Yahya et al., Use of soybean residue as a Color absorbent of Orange 7 frome aqueous Solution . Journal of Helth and Enviroment, Spring2011, Volume 4, Issue 2, Pages49-56. (In Persion)
21. Gautham P.Jeppu., Clement Prabhakar, T., 2012, A modified Langmuir-Freundlich isotherm model for simulating pH-dependent adsorption effects, Journal of contaminant hydrology, Vol. 129, pp. 46-53.
_||_
1. Sadeghi, Sayed Shams al-Din, Naderi Masoud, An Analysis of the Dimensions of Gavernment Security in Iran of the Twenty-First Century, State Research Spring 1395, Volume 2, Issue 5, pp 165-202. (In Persion)
2. Sadeghi, Seyed Kamal et al ; Estimation of Economic Footprint in Economic Sectors in Iran by Social Accounting Matrix Approch . Quantitative Economics, Winter ,1395, Volume 11, Issue 3, pages 81-111, (In Persion)
3. Sallaryan, Mohammad,Development of Water Resources and New Management Developments in Irrigation, Water and Sustinable Development, 1393, Volume 1, Issue 2. (In Persion)
4. Mortazavi, Seyed Mostafa et al., Water Resources Management and Sustinable Development. Case Study ;Rafsnjan Plain Water and West Water ,2011, Volume 22, Issue2, pages 126-131. (In Persion)
5. Marandi, Reza Ebrahim Zarandi, Mohammad Javad, Investigation of Biological Treatment of Acid Drinage Water of Sarcheshmeh Copper Mine Based on the Function of Reactors with Conscuative Operations (SBR) ,Journal of Enviromental Science and Technology, Autuman 2010, Volume 12, Issue 3, Pages 35-44. (In Persion)
6. Yavari, Mohsen et al., Removal ., of Heavy Metals from Wastewater from Solid Waste Indusries in Zanjan , 16th National Conference on Enviromental Helth in Iran, 1392, Oct.9-11 Tabriz, Iran. (In Persion)
7. Dehghani, Mansoure et al., Investigating the Concentration of Heavy Metals in Drinking Water Resources of Shiraz,16 th National Conference on Enviromental Health of Iran,. 1392, Octobrer 9-11, Tabriz, Iran. (In Persion)
8. Alizadh, Reza Abedini , Soda. Applications of Nanotechnology in Enviromental Engineering. Human and Enviromental, Summer 2010, Volume 8, Issue 2, Pages 3-11. (In Persion)
9. Karimi Takanlou, Leila et al., Evaluation of the Absorption Process of Cadmium Ions from Synthetic Sewage with synthesized magnetic nanoparticles , Journal of healthes and Enviroment, Oct 2014, Volume 7, Issue 2, Pages 84-171. (In Persion)
10. Hossein Shahi Bandri, Coral, Application of Nanotechnology in Surface Water Under ground, and Westwater Treatment , Human and Enviroment,Summer, 2012 , Volum 10, Issue 2, Pages 27-32. (In Persion)
11. Darban, A.K., Kianinia Y., Taheri-Nassaj, E., 2013, Synthesis of nano-alumina powder from impure kaolin and its application for arsenite removal from aqueous solutions, Journal of Environmental Health Science and Engineering, Vol. 11(1), pp. 1-11.
12. Srivastava, V., Weng C.H., Singh V.K., Sharma Y.C., 2011, Adsorption of nickel ions from aqueous solutions by nano alumina: kinetic, mass transfer, and equilibrium studies, Journal of Chemical & Engineering Data, Vol. 56(4), pp. 1414-1422.
13. Saber, O., 2012, Novel self assembly behavior for γ-alumina nanoparticles, Particuology, Vol.10(6), pp.744-750.
14. Hoseinian, F.S., Irannajad M., Javadi Nooshabadi, A., 2015, Ion flotation for removal of Ni (II) and Zn (II) ions from wastewaters, International Journal of Mineral Processing, Vol.143, pp. 131-137.
15. Saeedi Far, M., Vahabzadeh Roodsari, H., Zamini, A., Mirrasooli, E., Kazemi, R., 2012, The effects of diazinon on behavior and some hematological parameters of fry rainbow trout(Oncorhynchus mykiss), World Journal of Fish Marine Science, Vol. 4, pp. 369-375.
16. Oohadi, Vahid Reza,Amiri, Mohammad Enviromental Geothechnics of Nano Clays in Intraction With Heavy Metal Pollutions ,Civil Engineer, Winter 2010, Volume 42, Issue 3, Pages 29-36. (In Persion)
17. Talei Bejarbone , Fetane et al., Removal of Heavi Metal(Copper) using Spirulina Platensis by Taguchi Methode, Aquatic Ecology Journal, Autumn 2013, Volume 5, Issue 2, Pages 124-134 . (In Persion)
18. Vali Nezahad, Fatemh et al., Study of Heavi Metals (Cadmium. Crumium, Nikel, Lead, Zink) In Slamshahr Under Ground Water Resources and its distibitution Map in GIS Enviroment Journal of Enviromental Science and Technology, Autumn 1395, Volume 18, No 2, Pages 187-199. (In Persion)
19. Mallakootian, M., Almasi, A ., Hosseini, H., 2018, Pb and Co removal from paint industries effluent using wood ash, International Journal of Enviromental Science & Technology , Vol 5(2), pp 217-222.
20. Hamzh, Yahya et al., Use of soybean residue as a Color absorbent of Orange 7 frome aqueous Solution . Journal of Helth and Enviroment, Spring2011, Volume 4, Issue 2, Pages49-56. (In Persion)
21. Gautham P.Jeppu., Clement Prabhakar, T., 2012, A modified Langmuir-Freundlich isotherm model for simulating pH-dependent adsorption effects, Journal of contaminant hydrology, Vol. 129, pp. 46-53.