بررسی کارایی کربن‌فعال تولید‌شده از چوب انگور در حذف رنگ‌های راکتیو بلو 19 و راکتیو رد 198 از محلول آبی-مطالعات تعادلی و سنتیکی
محورهای موضوعی :
آلودگی محیط زیست (آب و فاضلاب)
مهران بیجاری
1
,
زهره علی محمدی
2
,
حبیب اله یونسی
3
,
نادر بهرامی فر
4
1 - کارشناسی‌ارشد آلودگی محیط زیست، دانشکده منابع طبیعی و علوم دریایی، دانشگاه تربیت مدرس، تهران، ایران
2 - کارشناسی‌ارشد آلودگی محیط زیست، دانشکده منابع طبیعی و علوم دریایی، دانشگاه تربیت مدرس، تهران، ایران
3 - استاد گروه محیط زیست، دانشکده منابع طبیعی و علوم دریایی، دانشگاه تربیت مدرس، تهران، ایران*(نویسنده مسول)
4 - دانشیار گروه محیط زیست، دانشکده منابع طبیعی و علوم دریایی، دانشگاه تربیت مدرس، تهران، ایران
تاریخ دریافت : 1395/09/07
تاریخ پذیرش : 1397/09/11
تاریخ انتشار : 1400/01/01
کلید واژه:
چوب انگور,
سیستم ناپیوسته,
کربن‌فعال,
رنگ راکتیو بلو 19,
راکتیو رد 198,
چکیده مقاله :
زمینه و هدف: رنگ‌های راکتیو از جمله پرکاربردترین رنگ‌ها در صنایع نساجی هستند. در فرآیند رنگرزی حدود 60 تا 70% از رنگ مصرفی بر روی الیاف تثبیت می‌شود. در آخرین مرحله آب‌شویی الیاف حدود 15-10 % از رنگ‌های راکتیو مصرفی وارد پساب شده و باعث بروز مشکلات زیست محیطی می‌گردند. لذا هدف از این مطالعه حذف رنگ‌های راکتیو بلو19 و راکتیو رد 198 با استفاده از کربن‌فعال تهیه‌شده از پسماند حاصل از هرس درختچه انگور در سیستم ناپیوسته است.روش بررسی: در این مطالعه کربن‌فعال با فعال‌ساز اسیدفسفریک در نسبت اشباع 1:2 و در دمای°C 400 سنتز شد. همچنین شرایط بهینه برای حداکثر جذب رنگ‌های راکتیو بلو19 و رد 198 در این مطالعه pH برابر 2، دوز جاذب g/l 05/0، غلظت اولیه رنگ mg/l300، دما C° 60، حجم محلول ml 200 و زمان تماس 120 دقیقه تعیین شد.یافته ها: نتایج نشان داد که نمونه کربن‌فعال با سطح ویژه m2/g 1950 و حجم کلی حفرات cm3/g 588/1 و توزیع 51% حفرات در محدوده میکروحفره با حداکثر ظرفیت جذب mg/g 1154 برای رنگ بلو 19 و mg/g 431 برای رنگ راکتیو 198 در شرایط بهینه از پتانسیل بالایی در حذف رنگ برخوردار است. همچنین داده‌های تعادلی رنگ راکتیو بلو 19 تطابق بیشتری با مدل فرندلیخ و داده‌های رنگ راکتیو رد 198 تطابق بهتری با مدل لانگمیر داشت. جذب هر دو رنگ نیز از مدل سینتیکی شبه مرتبه دوم پیروی نمود.نتیجه گیری: این مطالعه نشان داد کربن‌فعال تهیه‌شده از چوب انگور از پتانسیل بالایی در تصفیه پساب صنایع نساجی برخوردار است.
چکیده انگلیسی:
Background and Purpose: Reactive dyes are the most commonly used dyes in textile industry. During the dyeing process about 60 to 70 percent of consumer dye is fixed on the fibers. So about 10-15 % of consumed reactive dyes enters into the wastewater and causes environmental problems. The aim of this study was to remove Reactive Blue 19 and Reactive Red 198 dyes using activated carbon made from waste of tree pruning grapes in a batch system.Materials and Methods: In this study, activated carbon were synthesized with phosphoric acid in a ratio of 1: 2 at 400 C °. Also the optimum conditions for maximum adsorption of reactive Blue 19 and Red 198 dyes was determined (pH=2, adsorption dose= 0.05 g/l, dye concentration = 300 mg/l, temperature = 60°C, solution volume = 200 mL and contact time= 120 min).Finding: Batch adsorption results showed that activated carbon sample with a surface area 1950 m2/g and total pore volume 1.588 cm3/g and 51 percent pore size distribution in the range of micro-hole with the maximum adsorption capacity 1154 mg/g for Reactive Blue19 and 431 mg/g for Reactive Red 198 (In optimum condition) has great potential for the removal of dyes. Experimental data for Reactive Blue 19 are more compliance with Freundlich model and experimental data for Reactive Red 198 are more compliance with Langmuir model. Adsorption of dyes also be followed pseudo-second-order kinetic model.Discussion and Conclusion: The study showed activated carbon produced from annual pruning vineyards waste has high potential in the treatment of textile wastewater
منابع و مأخذ:
M.A.M. Salleh, D.K. Mahmoud, W.A.W.A. Karim, A. Idris, Cationic and anionic dye adsorption by agricultural solid wastes: A comprehensive review, Desalination, 280 (2011) 1-13.
G. Crini, P.-M. Badot, Application of chitosan, a natural aminopolysaccharide, for dye removal from aqueous solutions by adsorption processes using batch studies: A review of recent literature, Progress in Polymer Science, 33 (2008) 399-447.
M. Mohammed, A. Shitu, A. Ibrahim, Removal of Methylene Blue Using Low Cost Adsorbent: A Review, Research Journal of Chemical Sciences, In Press, (2014).
F. Çolak, N. Atar, A. Olgun, Biosorption of acidic dyes from aqueous solution by Paenibacillus macerans: Kinetic, thermodynamic and equilibrium studies, Chemical Engineering Journal, 150 (2009) 122-130
V.K. Gupta, Suhas, Application of low-cost adsorbents for dye removal – A review, Journal of Environmental Management, 90 (2009) 2313-2342.
Z. Aksu, Application of biosorption for the removal of organic pollutants: a review, Process Biochemistry, 40 (2005) 997-1026
M.A. Nahil, P.T. Williams, Pore characteristics of activated carbons from the phosphoric acid chemical activation of cotton stalks, Biomass and Bioenergy, 37 (2012) 142-149
Amini M, Younesi H, Bahramifar N. Biosorption of nickel (II) from aqueous solution by Aspergillus niger: response surface methodology and isotherm study. Chemosphere. (2009) 75(11):1483-91.
Thommes M. Physical adsorption characterization of nanoporous materials. Chemie Ingenieur Technik. 2010 Jul 1;82(7):1059-73.
E. Yagmur, M. Ozmak, Z. Aktas, A novel method for production of activated carbon from waste tea by chemical activation with microwave energy, Fuel, 87 (2008) 3278-3285
Zawadzki J. Infrared-spectroscopy in surface-chemistry of carbons. Chemistry and physics of carbon. 1989 Jan 1;21:147-380.
Ai L, Zhang C, Liao F, Wang Y, Li M, Meng L, Jiang J. Removal of methylene blue from aqueous solution with magnetite loaded multi-wall carbon nanotube: kinetic, isotherm and mechanism analysis. Journal of hazardous materials. 2011 Dec 30;198:282-90.
S. Senthilkumaar, P. Kalaamani, K. Porkodi, P.R. Varadarajan, C.V. Subburaam, Adsorption of dissolved Reactive red dye from aqueous phase onto activated carbon prepared from agricultural waste, Bioresource Technology, 97 (2006) 1618-1625.
K. Santhy, P. Selvapathy, Removal of reactive dyes from wastewater by adsorption on coir pith activated carbon, Bioresource Technology, 97 (2006) 1329-1336.
Y.S. Al-Degs, M.I. El-Barghouthi, A.H. El-Sheikh, G.M. Walker, Effect of solution pH, ionic strength, and temperature on adsorption behavior of reactive dyes on activated carbon, Dyes and Pigments, 77 (2008) 16-23.
Wang P, Ma Q, Hu D, Wang L. Removal of Reactive Blue 21 onto magnetic chitosan microparticles functionalized with polyamidoamine dendrimers. Reactive and Functional Polymers. 2015 Jul 31;91:43-50.
M. Mahboobeh, V. Rattan, K. Ameneh, P.H. Ahmad, Capacity of Activated Carbon Derived from Agricultural Waste in the Removal of Reactive Dyes from Aqueous Solutions, Carbon letters, 11 (2010) 169-175.
K.V. Kumar, A. Kumaran, Removal of methylene blue by mango seed kernel powder, Biochemical Engineering Journal, 27 (2005) 83-93.
N.K. Amin, Removal of direct blue-106 dye from aqueous solution using new activated carbons developed from pomegranate peel: Adsorption equilibrium and kinetics, Journal of Hazardous Materials, 165 (2009) 52-62.
W. Li, L.-b. Zhang, J.-h. Peng, N. Li, X.-y. Zhu, Preparation of high surface area activated carbons from tobacco stems with K2CO3 activation using microwave radiation, Industrial Crops and Products, 27 (2008) 341-347.
B.H. Hameed, A.A. Ahmad, Batch adsorption of methylene blue from aqueous solution by garlic peel, an agricultural waste biomass, Journal of Hazardous Materials, 164 (2009) 870-875.
Alimohammadi, Z., H. Younesi & N. Bahramifar Batch and Column Adsorption of Reactive Red 198 from Textile Industry Effluent by Microporous Activated Carbon Developed from Walnut Shells. Waste and Biomass Valorization, 1-16
F. Haghseresht, G. Lu, Adsorption characteristics of phenolic compounds onto coal-reject-derived adsorbents, Energy & Fuels, 12 (1998) 1100-1107.
P. Ding, K.-L. Huang, G.-Y. Li, Y.-F. Liu, W.-W. Zeng, Kinetics of adsorption of Zn(II) ion on chitosan derivatives, International Journal of Biological Macromolecules, 39 (2006) 222-227
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M.A.M. Salleh, D.K. Mahmoud, W.A.W.A. Karim, A. Idris, Cationic and anionic dye adsorption by agricultural solid wastes: A comprehensive review, Desalination, 280 (2011) 1-13.
G. Crini, P.-M. Badot, Application of chitosan, a natural aminopolysaccharide, for dye removal from aqueous solutions by adsorption processes using batch studies: A review of recent literature, Progress in Polymer Science, 33 (2008) 399-447.
M. Mohammed, A. Shitu, A. Ibrahim, Removal of Methylene Blue Using Low Cost Adsorbent: A Review, Research Journal of Chemical Sciences, In Press, (2014).
F. Çolak, N. Atar, A. Olgun, Biosorption of acidic dyes from aqueous solution by Paenibacillus macerans: Kinetic, thermodynamic and equilibrium studies, Chemical Engineering Journal, 150 (2009) 122-130
V.K. Gupta, Suhas, Application of low-cost adsorbents for dye removal – A review, Journal of Environmental Management, 90 (2009) 2313-2342.
Z. Aksu, Application of biosorption for the removal of organic pollutants: a review, Process Biochemistry, 40 (2005) 997-1026
M.A. Nahil, P.T. Williams, Pore characteristics of activated carbons from the phosphoric acid chemical activation of cotton stalks, Biomass and Bioenergy, 37 (2012) 142-149
Amini M, Younesi H, Bahramifar N. Biosorption of nickel (II) from aqueous solution by Aspergillus niger: response surface methodology and isotherm study. Chemosphere. (2009) 75(11):1483-91.
Thommes M. Physical adsorption characterization of nanoporous materials. Chemie Ingenieur Technik. 2010 Jul 1;82(7):1059-73.
E. Yagmur, M. Ozmak, Z. Aktas, A novel method for production of activated carbon from waste tea by chemical activation with microwave energy, Fuel, 87 (2008) 3278-3285
Zawadzki J. Infrared-spectroscopy in surface-chemistry of carbons. Chemistry and physics of carbon. 1989 Jan 1;21:147-380.
Ai L, Zhang C, Liao F, Wang Y, Li M, Meng L, Jiang J. Removal of methylene blue from aqueous solution with magnetite loaded multi-wall carbon nanotube: kinetic, isotherm and mechanism analysis. Journal of hazardous materials. 2011 Dec 30;198:282-90.
S. Senthilkumaar, P. Kalaamani, K. Porkodi, P.R. Varadarajan, C.V. Subburaam, Adsorption of dissolved Reactive red dye from aqueous phase onto activated carbon prepared from agricultural waste, Bioresource Technology, 97 (2006) 1618-1625.
K. Santhy, P. Selvapathy, Removal of reactive dyes from wastewater by adsorption on coir pith activated carbon, Bioresource Technology, 97 (2006) 1329-1336.
Y.S. Al-Degs, M.I. El-Barghouthi, A.H. El-Sheikh, G.M. Walker, Effect of solution pH, ionic strength, and temperature on adsorption behavior of reactive dyes on activated carbon, Dyes and Pigments, 77 (2008) 16-23.
Wang P, Ma Q, Hu D, Wang L. Removal of Reactive Blue 21 onto magnetic chitosan microparticles functionalized with polyamidoamine dendrimers. Reactive and Functional Polymers. 2015 Jul 31;91:43-50.
M. Mahboobeh, V. Rattan, K. Ameneh, P.H. Ahmad, Capacity of Activated Carbon Derived from Agricultural Waste in the Removal of Reactive Dyes from Aqueous Solutions, Carbon letters, 11 (2010) 169-175.
K.V. Kumar, A. Kumaran, Removal of methylene blue by mango seed kernel powder, Biochemical Engineering Journal, 27 (2005) 83-93.
N.K. Amin, Removal of direct blue-106 dye from aqueous solution using new activated carbons developed from pomegranate peel: Adsorption equilibrium and kinetics, Journal of Hazardous Materials, 165 (2009) 52-62.
W. Li, L.-b. Zhang, J.-h. Peng, N. Li, X.-y. Zhu, Preparation of high surface area activated carbons from tobacco stems with K2CO3 activation using microwave radiation, Industrial Crops and Products, 27 (2008) 341-347.
B.H. Hameed, A.A. Ahmad, Batch adsorption of methylene blue from aqueous solution by garlic peel, an agricultural waste biomass, Journal of Hazardous Materials, 164 (2009) 870-875.
Alimohammadi, Z., H. Younesi & N. Bahramifar Batch and Column Adsorption of Reactive Red 198 from Textile Industry Effluent by Microporous Activated Carbon Developed from Walnut Shells. Waste and Biomass Valorization, 1-16
F. Haghseresht, G. Lu, Adsorption characteristics of phenolic compounds onto coal-reject-derived adsorbents, Energy & Fuels, 12 (1998) 1100-1107.
P. Ding, K.-L. Huang, G.-Y. Li, Y.-F. Liu, W.-W. Zeng, Kinetics of adsorption of Zn(II) ion on chitosan derivatives, International Journal of Biological Macromolecules, 39 (2006) 222-227
