ابرخازن‌های پایه مکسن و چشمانداز آینده آن
محورهای موضوعی : شیمی کاربردی
طیبه محبی
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مجید میرزایی
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مسعود همدانیان
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1 - دانشجوی دکتری گروه شیمی، دانشگاه کاشان، کاشان، ایران.
2 - استادیار گروه پژوهشی مواد غیرفلزی، پژوهشگاه نیرو، تهران، ایران.
3 - عضو هیات علمی گروه نانوشیمی(دانشیار)، دانشگاه کاشان، گروه شیمی،کاشان، ایران صندوق پستی: 51167-87317
کلید واژه: چندسازه, مکسن, ابرخازن,
چکیده مقاله :
مکسنها (MXene) به‌دلیل ساختار بی‌همتا و گروههای عامل شیمیایی قابل‌تنظیم، یک سری ویژگی شگفتانگیز دارند. کاربرد مکسنها در ذخیره‌سازی انرژی الکتروشیمیایی بهویژه نشان‌دادن پتانسیل بالا در کاربردهای ابرخازن توجه ویژهای را به خود جلب کرده است. در مقایسه با سایر مواد، مکسنها انعطاف مکانیکی بالا، چگالی انرژی بالا و کارایی الکتروشیمیایی خوبی دارند. بنابراین، به ویژه به‌عنوان مواد الکترود برای ابرخازن‌ها مناسب هستند. با این حال، مشابه سایر مواد دو بعدی، به‌دلیل نیروهای قوی واندروالس، لایه‌های مکسن به‌ناچار انباشته می‌شوند که منجر به از دستدادن شدید مکان‌های فعال الکتروشیمیایی می‌شوند. اگر بتوان تجمع لایه‌های مکسن را به‌طور مؤثری مهار کرد، کارایی الکتروشیمیایی آنها افزایش می‌یابد. بهینهسازی ساختاری مکسنها و دوپه‌شدن آنها با مواد دیگر دو راهبرد موثر چشمگیر است. این مقاله، پیشرفت‌های اخیر در سنتز مکسن، ویژگی اساسی، و مواد چندسازه را با تمرکز بر آخرین کارایی الکتروشیمیایی الکترودها/دستگاه‌های مبتنی بر مکسن مرور می‌کند و چالش‌ها و فرصت‌های جدیدی را که مکسن در زمینه ذخیره‌سازی انرژی با آن مواجه است، ارائه می‌کند.
MXenes have a series of amazing properties due to their unique structure and tunable chemical functional groups. The application of MXenes in electrochemical energy storage, especially showing high potential in supercapacitor applications, has attracted special attention. Compared to other materials, MXenes have high mechanical flexibility, high energy density, and good electrochemical performance, so they are especially suitable as electrode materials for supercapacitors. However, similar to other 2D materials, due to strong van der Waals forces, MXene layers inevitably undergo stacking, leading to a severe loss of electrochemically active sites. If the layers of MXenes can be suppressed effectively, their electrochemical performance will be enhanced. Structural optimization of MXenes and composite doping of MXenes with other materials are two strategies with significant effects. This review summarizes recent advances in MXene synthesis, fundamental properties, and composite materials with a focus on the latest electrochemical performance of MXene-based electrodes/devices and presents new challenges and opportunities that MXene faces in energy storage
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