ارایه روشهای بهینه جهت تصفیه آب و پساب حاوی رنگهای گوگردی
محورهای موضوعی : آب و محیط زیستسحر طبیبیان 1 , اعظم پیرکرمی 2
1 - استادیار، گروه کشاورزی و منابع طبیعی، دانشگاه پیام نور، تهران، ایران.*(مسئول مکاتبات)
2 - دانشجوی دکتری، گروه پژوهشی رنگ و محیط زیست، موسسه پژوهشی علوم وفناوری رنگ، تهران.
کلید واژه: رنگهای گوگردی, پساب, روشهای فیزیکی وشیمیایی, روشهای بیولوژیکی,
چکیده مقاله :
رنگ های گوگرد ارزان قیمت هستند و به طور عمده برای رنگ آمیزی مواد سلولزی منسوجات و یا مخلوط الیاف سلولزی مورد استفاده قرار میگیرند. سولفید سدیم نسبتاً ارزان بوده و از عوامل کاهنده سنتی محسوب می شود و برای رنگرزی رنگ های گوگردی مورد استفاده قرار می گیرد، اما لمس آن، سمی و خطرناک است. استعمال آن ممکن است بقایای مضری در پارچه تکمیل شده به جا بگذارد و پساب هایی تولید میکند که تصفیه آن دشوار است و به محیط زیست آسیب میرساند. صنایع نساجی با هزینههای بالای آب و تصفیه پساب، و همچنین قوانین سختگیرانه محیط زیستی مواجه هستند. در این بررسی، انواع روشها، از جمله روشهای فیزیکی، شیمیایی و بیولوژیکی از نظر کاربردشان برای تصفیه پساب صنعتی حاوی رنگ های گوگردی مورد بررسی قرار گرفت. این مطالعه با پیشنهاداتی برای اقدامات بیشتری که میتوان جهت بهبود فرآیندهای تصفیه از هر دو دیدگاه اقتصادی و فنی انجام داد، به پایان میرسد.
Abstract Sulfur dyes are inexpensive and mainly used for coloring cellulosic textile materials or mixtures of cellulosic fibers. Sodium sulfite is relatively inexpensive and considered as traditional reducing agents and used for sulfur dyes and dyeing, But touch it, is toxic and dangerous.Using it may be Leave harmful residues on fabrics completed and and produces wastewater which it’s treatment is difficult and damage to the environment. Textile industries are met with high cost of water and wastewater treatment, as well as stringent environmental regulations. In this study, a variety of methods, including methods of physical, chemical and biological treatment of industrial wastewater containing paint application of sulfur was investigated This study concludes with recommendations for additional measures to improve treatment processes that can be done from both a technical and economic point of view.
1- E. Croissant, L.M.F. Bretonniere, S. Yoshioka, H.M. Tobin, Sulfur dyes, in: J. Senior, R.A. Guest, W.E. Wood (Eds.), Kirk–Othmer Encyclopedia of Chemical Technology, John Wiley, New York, 2000, pp. 215–216. pp. 1 and 18–19.
2- G. Shankarling, R. Paul, J. Thampi, Novel dyes and commercial forms, Colourage 44 (1997) 71–74.
3- C. Heid, K. Holoubek, R. Klein, Sulfur dyes – chemical constitution, in: K. Hunger (Ed.), Industrial Dyes: Chemistry, Properties, Applications, Wiley- VCH, Weinheim, 2003, pp. 215–216.
4- C.A. Fewson, Biodegradation of xenobiotic and other persistent compounds: the causes of recalcitrance, Trends Biotechnol. 6 (1988) 148–153
5- F. He, W. Hu, Y. Li, Biodegradation mechanisms and kinetics of azo dye 4BS by a microbial consortium, Chemosphere 57 (2004) 293–301.
6- J. Robinson, Sulfur dyes and the environment, J. Soc. Dyers Colorists 111 (1995) 172–175.
7- R. Han, S. Zhang, W. Zhao, X. Li, X. Jian, Treating sulfur black dye wastewaterwith quaternized poly (phthalazinone ether sulfone ketone) nanofiltration membranes, Sep. Purif. Technol. 67 (2009) 26–30.
8- O.O. Ogunlaja, O. Aemere, Evaluating the efficiency of a textile wastewater treatment plant located in Oshodi (Lagos), African J. Pure Appl. Chem. 3 (2009) 189–196.
9- Sodium thiosulfate, Material Safety Data Sheet, EUSA-180, September 2007, p. 1.
10- Kim, T.H., Park, C., Shin, E.-B., Kim, S., 2002, Decolorization of disperse and reactive dyes by continuous electrocoagulation process, Desalination. 150, pp. 165–175.
11- I.M. Banat, P. Nigam, D. Singh, R. Marchant, Microbial decolorization of textile-dye-containing effluents: a review, Biores. Technol. 58 (1996) 217– 227.
12- Lili L., Xueling C., Yuqing W., Dawei L., Dandan H., Synthesis of organo-functionalized magnetic microspheres and application foranionic dye removal. Journal of the Taiwan Institute of Chemical Engineers 44 (2013) 67–73.
13- O. Marmagne, C. Coste, Color removal from textile plant effluents, Am. Dyest. Rep. 85 (1996) 15–21.
14- W. Rudolfs, W.H. Baumgartner, Notes on Precipitation of Black Sulfur Dye Waste, New Jersey Agricultural Experiment Station, New Brunswick, NJ, USA, 1931.
15- Lucas, M. S., Peres, J. A., Puma, G.L., 2011, Treatment of winery wastewater by ozone-based advanced oxidation processes (O3, O3/UV and O3/UV/H2O2) in a pilot-scale bubble column reactor and process economics, Separation and Purification Technology, 72, pp. 235–241.
16- Katsoyiannis, I.A., Canonica, S., Gunten, U., 2011, Efficiency and energy requirements for the transformation of organic micropollutants by ozone, O3/H2O2 and UV/H2O2., Water Research, 46, pp. 3811–3822.
17- Kim, I., Yamashita, N., Tanaka, H., 2009, Photodegradation of pharmaceuticals and personal care products during UV and UV/H2O2 treatments, Chemosphere, 77, pp. 518–525.
18- V.V. Sethuraman, B.C. Raymahashay, Color removal by clays: kinetic study of adsorption of cationic and anionic dyes, Ind. J. Technol. 9 (1985) 643–649.
19- K. L. M. Gleisy, S. D. Maria Angélica, L. Rafael, d. S. Edison Antonio, d. M. L. Oswaldo Curty, Dynamic isotherms of dye in activated carbon, Materials Research 3 (2008) 1516-1439.
20- J. Jia, J. Yang, J. Liao, W. Wang, Z. Wang, Treatment of dyeing wastewater with ACF electrodes, Water Res. 33 (1999) 881–884.
21- M. von Sperling, V.H. Freire, C.A. de Lemos Chernicharo, Performance evaluation of a UASB-activated sludge system treating municipal wastewater, Water Science and Technology 43 (2001) 323–328.
22- Y. Fu, T. Viraraghavan, Fungal decolorization of dye wastewaters, Biores. Technol. 79 (2001) 251–262.
23- M. Imran, M.J. Asad, S.H. Hadri, S. Mehmood, Production and industrial applications of laccase enzyme, J. Cell Mol. Biol. 10 (2012) 1–11.
24- J.N. Chakraborty, G. Dhiman, Effectiveness of laccase in the oxidation and recovery of sulfur dyes, Text. Res. J. (published, online 26 July 2012)
25- D. Brady, A. Stoll, J.R. Duncan, Biosorption of heavy metal cations by nonviable yeast biomass, Environ. Technol. 15 (1994) 429–438.
26- J.K. Polman, C.R. Breckenridge, Biomass-mediated binding and recovery of textile dyes from waste effluents, Text. Chem. Colorists 28 (1996) 31–35.
27- M.K. Keung, Bacterium useful in the removal of sulfur black dye from a substrate, US Patent No. 5610064, 1997.
28- S. Andleeb, N. Atiq, M.I. Ali, R.R.U. Hussnain, M. Shafique, B. Ahmad, P.B. Ghumro, M. Hussain, A. Hameed, S. Ahmad, Biological treatment of textile effluent in stirred tank bioreactor, Int. J. Agric. Biol. 12 (2010) 256–260.
29- S.U. Jadhav, M.U. Jadhav, A.N. Kagalkar, S.P. Govindwar, Decolorization of brilliant blue G dye mediated by degradation of the microbial consortium of Galactomyces geotrichum and Bacillus sp, J. Chin. Inst. Chem. Eng. 39 (2008) 563– 570.
30- S. Galai, F. Limam, M.N. Marzouki, Decolorization of an industrial effluent by free and immobilized cells of Stenotrophomonas maltophilia AAP56: implementation of efficient down flow column reactor, World J. Microbiol. Biotechnol. 26 (2010) 1341–1347.
31- B. Santhosh, Treatment of textile wastewater containing black sulfur dye using ceramic membrane based separation process, Scribd 2011.
32- B. Santhosh, Potential use of Eichhornia crassipes for treatment of highly toxicsulfur black effluent, Scribd2011.